Publications ( Cited by SCI )

Kinetics of liquid phase synthesis of tert-amyl methyl ether from tert-amyl alcohol and methanol catalyzed by ion exchange resin




作者: Yang BL, Maeda M, Goto S
发表/完成日期: 1998-03-03
期刊名称: INTERNATIONAL JOURNAL OF CHEMICAL KINETICS
期卷: 30 (2)
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论文简介
Synthesis of tert-amyl methyl ether (TAME) from methanol (MeOH) and tert-amyl alcohol (TAA) in the liquid phase was studied by using an ion exchange resin, Amberlyst15 (A15) in the H+ form. Experiments were carried out in a stirred batch reactor under atmospheric pressure. The effects of catalyst size, agitation speed, temperatures, feed ratio and water on the reaction rate were investigated. Both of intraparticle and external diffusion effects could be neglected in this System. The dehydration of TAA could be decreased by increasing the ratio of MeOH/TAA and the reaction rates were greatly inhibited by water.
IDS Number: YR942