null

Publications ( Cited by SCI )

论文标题    On the oxidative coupling of methane with carbon dioxide over CeO2/ZnO nanocatalysts
作者    He YJ, Yang BL, Cheng GX
发表/完成日期    2004-12-14
期刊名称    CATALYSIS TODAY
期卷    98 (4)
相关文章   
论文简介    The nano-CeO2/ZnO catalysts were prepared using a novel combination of homogeneous precipitation with micro-emulsion for oxidative coupling of methane with CO2 as an oxidant. The prepared catalysts were compared with those prepared using the conventional impregnation. The catalysts prepared in two ways were characterized with FTIR, TEM, XRD and CO2-TPD. The effects of the reaction temperature, the amount of ZnO doped in the catalysts and the average size were investigated. The experimental investigation demonstrated that methane conversion over the nano-CeO2/ZnO catalysts prepared by the combined technique was higher than that obtained over catalysts prepared by the conventional impregnation. A better low-temperature activity has also been achieved over the nanocatalysts. There was no clear trend between the average size of nano-CeO2/ZnO catalysts and their catalytic performance but methane conversion increased with increasing fractal dimension of nanocatalysts. (C) 2004 Elsevier B.V. All rights reserved. IDS Number: 882AR
返回