发表文章

  

Publication @ XJTU

2019

64.   Yang, J.-C.;  Chen, L.; Yang, F.;  Li, P.-F. Guo, L.-N.*  

        Copper-Catalyzed Borylation of Cycloalkylsilyl Peroxides via Radical C-C Bond Cleavage.   

       Org. Chem. Front. 2019DOI: 10.1039/C9QO00472F  

 

63.   Ma, Z.-Y.;  Guo, L.-N.; You, Y.; Yang, F.; Hu, M.;  Duan, X.-H.*

        Visible Light Driven Alkylation of C(sp3)−H Bonds Enabled by 1,6-Hydrogen Atom Transfer/Radical Relay Addition. 

        Org. Lett. 2019DOI: 10.1021/acs.orglett.9b01804    

 

62.  Tang. Y.-Q.; Yang, J.-C.; Wang, L.; Fan, M.;  Guo, L.-N.* 

       Ni-Catalyzed Redox-Neutral Ring-Opening/Radical Addition/Ring-Closing Cascade of Cycloketone Oxime Esters and Vinyl Azides.    

       Org. Lett. 2019DOI: 10.1021/acs.orglett.9b01773.    

 

61.  Yang, L.; Zhang, J.-Y.; Duan, X.-H.; Gao, P.; Jiao, J.;  Guo, L.-N.*  

       Copper-Catalyzed Cyanoalkylation of Amines via C–C Bond Cleavage: An Approach for C(sp3)–N Bond Formations.    

       J. Org. Chem. 2019DOI: 10.1021/acs.joc.9b01084.

 

60.  Chen, L.; Guo, L.-N.; Ma, Z.-Y.; Gu, Y.-R.; Zhang, J.; Duan, X.-H. 

       Iminyl Radical-Triggered 1,5-Hydrogen-Atom Transfer/Heck-Type Coupling by Visible-Light Photoredox Catalysis.

       J. Org. Chem. 2019, 84, 6475.

 

59.  Gu, Y.-R.; Duan, X.-H.; Chen, L.;  Ma, Z.-Y.;  Gao, P.; Guo, L.-N.*  

       Iminyl Radical-Triggered Intermolecular Distal C(sp3)−H Heteroarylation via 1,5-Hydrogen-Atom Transfer (HAT) Cascade

       Org. Lett. 2019, 21, 917.

 

58.  Zhang, J.-J.; Duan, X.-H.; Wu, Y.;  Yang, J.-C.;  Guo, L.-N.*  

       Transition-Metal Free C–C Bond Cleavage/Borylation of Cycloketone Oxime Esters. 

       Chem. Sci. 2019, 10, 161ESI收录

 

2018

 

57.  Ma, Z.-Y.; Guo, L.-N.; Gu. Y.-R.; Chen. L.; Duan, X.-H.

       Iminyl Radical-Mediated Controlled Hydroxyalkylation of Remote C(sp3)-H Bond via Tandem 1,5-HAT and Difunctionalization of

       Aryl Alkenes. 

       Adv. Synth. Catal. 20183604341.

 

56.  Zhao, J.-F.;  Duan, X.-H.; Gu, Y.-R.; Gao, P.;  Guo, L.-N.*   

       Iron-Catalyzed Decarboxylative Olefination of Cycloketone Oxime Esters with α,β-Unsaturated Carboxylic Acids via  C-C

       Bond Cleavage.

       Org. Lett., 2018204616.

 

55.  Zhang, J.-Y.; Duan, X.-H.; Yang, J.-C.; Guo, L.-N.*  

       Redox-Neutral Cyanoalkylation/Cyclization of Olefinic 1,3‑Dicarbonyls with Cycloketone Oxime Esters: Access to Cyanoalkylated

       Dihydrofurans.

        J. Org. Chem. 201883, 4239.

 

54.  Zhao, J.-F.; Gao, P.; Duan, X.-H.; Guo, L.-N.* 

       Iron-Catalyzed Ring-Opening/Allylation of Cyclobutanone Oxime Esters with Allylic Sulfones

       Adv. Synth. Catal. 2018360, 1775. ESI收录

 

53.  Yang, J.-C.; Zhang, J.-Y.; Zhang, J.-J.; Duan, X.-H.; Guo, L.-N.*  

       Metal-Free, Visible-Light-Promoted Decarboxylative Radical Cyclization of Vinyl Azides with  N‑Acyloxyphthalimides 

       J. Org. Chem. 201883, 1598.

 

52.  Wu, J.; Zhang, J.-Y.; Gao, P.; Xu, S.-L.;  Guo, L.-N.*  

       Copper-Catalyzed Redox-Neutral Cyanoalkylarylation of Activated Alkenes with Cyclobutanone Oxime Esters.

       J. Org. Chem. 201883, 1046ESI收录

 

51.  Yang, L.; Gao, P.; Duan, X.-H.; Gu, Y.-R.; Guo, L.-N.*  

       Direct C−H Cyanoalkylation of Quinoxalin-2(1H)‑ones via Radical C−C Bond Cleavage.

       Org. Lett., 201820, 1034ESI收录

 

2017

 

50.  Gu, Y.-R.;  Duan, X.-H.; Yang, L.;  Guo, L.-N.*  

       Direct C−H Cyanoalkylation of Heteroaromatic N-Oxides and Quinones via C−C Bond Cleavage of Cyclobutanone Oximes.

       Org. Lett., 2017, 19, 5908.

 

49.  Zhang, J.-J.;  Yang, J.-C.;  Guo, L.-N.; Duan, X.-H 

       Visible-Light-Mediated Dual Decarboxylative Coupling of Redox-Active Esters with α,β-Unsaturated Carboxylic Acids.

       Chem. Eur. J., 201723,10259. Hot Paper

 

48.  Zhao, J.-F.; Duan, X.-H.; Guo, L.-N.*  

       Recent Advances in Persulfates-Promoted Radical Reaction.

       Chin. J. Org. Chem., 201737, 2498. Invited Article

 

2016

 

47.  Yang, J.-C.; Zhang, J.-J.; Guo, L.-N.* 

       Copper-catalyzed oxidative cyclization of vinyl azides with benzylic Csp3–H bonds for the synthesis of substituted phenanthridines

       Org. Biomol. Chem., 2016, 14, 9806.

 

46.  Guo, L.-N.; Wang, H.; Duan, X.-H.* 

       Recent Advances in Catalytic Decarboxylative Acylation Reactions via a Radical Process

       Org. Biomol. Chem., 2016, 14, 7380.  Invited Article

       This article is part of themed collection: 2016 Hot Articles in Organic and Biomolecular Chemistry

 

45.  Guo, L.-N.;* Deng, Z.-Q.; Wu, Y.; Hu, J.

       Transition-Metal Free Alkylarylation of Acrylamides Initiated by Radical C–C Bond Cleavage of the Tertiary Cycloalkanols

       RSC Adv., 2016, 6, 27000.

 

44.  Guo, L.-N.;*  Gu, Y.-R.; Yang, H.; Hu, J.

       Transition-Metal Free Thiocyanooxygenation of Functionalized Alkenes: Facile Routes to SCN-Containing Dihydrofurans and

        Lactones

       Org. Biomol. Chem., 2016, 14, 3098.

43.  Wang, H.; Guo, L.-N.; Duan, X.-H.*

        Palladium-Catalyzed Alkylarylation of Acrylamides with Unactivated Alkyl Halides

        J. Org. Chem. 2016, 81, 860-867.

 

2015

 

42.  Zhao, J.-F.; Duan, X.-H.; Yang, H.;  Guo, L.-N.*  

       Transition-Metal-Free Oxyfluorination of Olefinic Amides for the Synthesis of Fluorinated Heterocycles

       J. Org. Chem. 2015, 80, 11149-11155.

       Highlighted in X-MOL @ http://www.x-mol.com/news/1612

 

41.  Wang, S.; Guo, L.-N.; Wang, H. Duan, X.-H.*

       Alkynylation of Tertiary Cycloalkanols via Radical C−C Bond Cleavage: A Route to Distal Alkynylated Ketones

 Org. Lett. 2015, 17, 4798-4801.

 Highlighted in Organic-Chemistry @http://www.organic-chemistry.org/abstracts/lit5/138.shtm 

 

40.  Wang, S.; He, L.-Y.; Guo, L.-N.*  

       K2S2O8-Mediated Oxidative Radical Cyclization of 1,3-Dicarbonyl Compounds with Styrenes for the Synthesis of Dihydrofurans

       Synthesis 2015, 47, 3191-3197. 

       Highlighted in SynFacts 2015, 11(12), 1257.

       Highlighted in Organic-Chemistry @ http://www.organic-chemistry.org/Highlights/2016/11April.shtm

 

39.  Wang, H.; Guo, L.-N.; Wang, S. Duan, X.-H.*

        Decarboxylative Alkynylation of alpha‑Keto Acids and Oxamic Acids in Aqueous Media

       Org. Lett. 2015, 17, 3054-3057. 

       Highlighted in X-MOL @  http://www.x-mol.com/news/726

 

38.  Yang, Y.; Duan, X.-H.; Zhao, J.-F. Guo, L.-N.* 

        Transition-Metal-Free Tandem Radical Thiocyanooxygenation of Olefinic Amides: A New Route to SCN-Containing Heterocycles.

        Org. Lett. 2015, 17, 1998-2001. ESI收录 

 

37.  Guo, L.-N.;*  Wang, S.; Duan, X.-H.; Zhou, S.-L.

       Iron-Catalyzed Tandem Cyclization of Olefinic Dicarbonyl Compounds with Benzylic Csp3–H Bonds for the Synthesis of

       Dihydrofuran.

       Chem. Commun. 2015, 51, 4803-4806. ESI收录

 

36. Wang, H.; Zhou, S.-L.; Guo, L.-N.; Duan, X.-H.*

       Diacylation of Coumarins by Silver-Catalyzed Decarboxylative Cross-Coupling.

      Tetrahedron 2015, 71, 630-636.

 

2014

 

35. Yang, H.; Guo, L.-N.; Duan, X.-H.

      Silver-Catalyzed Tandem Radical Acylarylation of Cinnamamides in Aqueous Media.

      RSC. Adv. 2014, 4, 52986-52990.

 

34. Zhou, S.-L.; Guo, L.-N.; Duan, X.-H.*

      Copper-Catalyzed Regioselective Cross-Dehydrogenative Coupling of Coumarins with Benzylic Csp3-H Bonds.

      Eur. J. Org. Chem. 2014, 8094-8100.

 

33. Wang, H.; Guo, L.-N.; Duan, X.-H.*

       Silver-Catalyzed Decarboxylative Acylfluorination of Styrenes in Aqueous Media.

       Chem. Commun. 2014, 50, 7382-7384.

 

32. Zhou, S.-L.; Guo, L.-N.; Wang, S.; Duan, X.-H.*

      Copper-Catalyzed Tandem Oxidative Cyclization of Cinnamamides with Benzyl Hydrocarbons through Cross Dehydrogenative

      Coupling.

      Chem. Commun. 2014, 50, 3589-3591. ESI收录

 

2013

 

31. Wang, H.; Guo, L.-N.;*  Duan, X.-H.

      Metal-Free Oxidative Spirocyclization of Hydroxymethylacrylamide with 1,3-Dicarbonyl Compounds: A New Route to Spirooxindoles.

      Org. Lett. 2013, 15, 5254-5257.

      Highlighted in SynFacts 2013, 9(12), 1274.

 

30. Wang, H.; Guo, L.-N.;*  Duan, X.-H.

       Silver-Catalyzed Oxidative Coupling/Cyclization of Acrylamides with 1,3-Dicarbonyl Compounds.

       Chem. Commun. 2013, 49, 10370-10372.

       Highlighted in SynFacts 2013, 9(12), 1273.                

 

29. Meng, Y.; Guo, L.-N.;*  Wang, H.; Duan, X.-H.*

      Metal-Free Oxidative Hydroxyalkylarylation of Activated Alkenes by Direct sp3 C-H Functionalization of Alcohols.

      Chem. Commun. 2013, 49, 7540-7542. ESI收录

 

28. Zhou, S.-L.; Guo, L.-N.;*  Wang, H.; Duan, X.-H.*

      Copper-Catalyzed Oxidative Benzylarylation of Acrylamides by Benzylic C-H Bond Functionalization for the Synthesis of Oxindoles.

      Chem. Eur. J. 2013, 19, 12970-12973. ESI收录

 

27. Wang, H.; Guo, L.-N.;*  Duan, X.-H.

       Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media.

      Adv. Synth. Catal. 2013, 355, 2222-2226. ESI收录

 

26. Wang, H.; Guo, L.-N.;*  Duan, X.-H.

       Copper-Catalyzed Oxidative Condensation of α-Oxocarboxylic Acids with Formamides: Synthesis of α-Ketoamides.

       Org. Biomol. Chem. 2013, 11, 4573-4576.  

 

25. Zhang, S.; Guo, L.-N.;*  Wang, H.; Duan, X.-H.* 

      Decarboxylative Bu4NI-atalyzed Decarboxylative Acyloxylation of an sp3 C–H Bond Adjacent to a Heteroatom with α-Oxocarboxylic

      Acids.

      Org. Biomol. Chem. 2013, 11, 4308-4311.

      Top ten accessed articles during the 2nd quarter of 2013 (April – June)

 

2012

 

24. Wang, H.; Guo, L.-N.;*  Duan, X.-H.* 

       Decarboxylative Acylation of Cyclic Enamides with α-Oxocarboxylic Acids by Palladium-Catalyzed C-H Activation at Room

       Temperature.

       Org. Lett. 2012, 14, 4358-4361. ESI收录 

 

 



Cooperation with LZU and LMU

 

23. Guo, L.-N.; Duan, X.-H.; Liang, Y.-M.

      Palladium-Catalyzed Cyclization of Propargylic Compound.

     Acc. Chem. Res., 2011, 44, 111-122.

22. Thaler, T.; Guo, L.-N.; Mayer, P.; Knochel, P.

     Highly Diastereoselective Csp3-Csp Cross-Couplings between 1,3- and 1,4-Substituted Cyclohexylzinc Reagents and Bromoalkynes via

     Remote Stereocontrol.

     Angew. Chem., Int. Ed. 2011, 50, 2174-2177.

 

 Ph.D and Post-Doc


21.  Thaler, T.; Guo, L.-N.; Steib, A. K.; Paducan, M.; Karaghiosoff, K.; Mayer, P.; Knochel, P. Sulfoxide–Alkene Hybrids: A New Class of Chiral Ligands for the Hayashi–Miyaura  Reaction. Org. Lett. 2011, 13, 3182-3185.

20. Hu, J.; Zhao, N.; Yang, B.; Wang, G.; Guo, L.-N.; Liang, Y.-M., Yang S.-D. Copper-Catalyzed C–P Coupling through Decarboxylation. Chem. Eur. J. 2011, 17, 5516-5521.
19. Guo, L.-N.; Gao, H. Mayer, P.; Knochel, P. Preparation of Organoaluminum Reagents from Propargylic Bromides and Aluminum Activated by PbCl2 and Their Regio- and Diastereoselective Addition to Carbonyl Derivatives. Chem. Eur. J. 2010, 16. 9829-9834.
18. Hu, J.; Wang, X.-C.; Guo, L.-N.; Hu, Y.-Y.; Liu, X.-Y.; Liang, Y.-M. Pd/C-Catalyzed Cyclization/Isomerization: A New Route to 2-Aroyl-3-vinyl Benzo[b]furans via Carbon-Carbon Bond Formation. Catal. Commun. 2010, 11, 346–350.
17. Hu, Y.-Y.; Hu, J.; Wang, X.-C.; Guo, L.-N.; Shu, X.-Z; Niu, Y.-N.; Liang, Y.-M. Copper-catalyzed tandem synthesis of [1,2,3]triazolo[5,1-a]isoquinolines and their transformation to 1,3-disubstituted isoquinolines Tetrahedron. 2010, 66, 80-86.
16. Bian, Y.-J.; Liu, X.-Y.; Ji, K.-G.; Shu, X.-Z; Guo, L.-N.; Liang, Y.-M. Efficient synthesis of highly substituted pyrroles based on the tandem reactions: intermolecular amination and Pd(II)-catalyzed intramolecular hydroamidation. Tetrahedron. 2009, 65, 1424-1429.
15. Guo, L.-N.; Duan, X.-H.; Hu, J.; Bi, H.-P.; Liu, X.-Y.; Liang, Y.-M. Synthesis of Indene and Naphthalene Derivatives via a Palladium-Catalyzed Dmino Carbopalladation/ Cyclization/Coupling Process. Eur. J. Org. Chem. 2008, 1418-1425.
14. Bi, H.-P.; Guo, L.-N.; Gou, F-R; Duan, X.-H.; Liu, X.-Y.; Liang, Y.-M. Highly Regio- and Stereoselective Synthesis of Indene and Benzo[b]furan Derivatives via a Pd-Catalyzed Carboannulation of Propargyl Carbonates with Nucleophiles. J. Org. Chem. 2008, 73, 4713-4716.
13. Gou, F.-R.; Bi, H.-P.; Guo, L.-N.; Guan, Z-H; Liu, X.-Y.; Liang Y.-M. New Insight into Ni(II)-Catalyzed Cyclization Reactions of Propargylic Compounds with Soft Nucleophiles: Novel Indenes Formation. J. Org. Chem. 2008, 73, 3837-3841.
12. Shu, X.-Z; Liu, X.-Y.; Xiao, H.-Q.; Ji, K.-G.; Guo, L.-N.; Liang, Y.-M. Tandem Gold (III)-Catalyzed Amination-Intramolecular Hydroamination Reactions of 1-En-4-yn-3-ols with Sulfonamides: Efficient Approach to Highly Substituted Pyrroles. Adv. Synth. Catal. 2008, 350, 243-248.
11. Guo, L.-N.; Duan, X.-H.; Liu, X.-Y.; Hu, J.; Bi, H.-P.; Liang, Y.-M. Synthesis of Fused Polycycles from Propargylic Compounds with Terminal Alkynes via a Palladium-Catalyzed Tandem C-H Activation/Biscyclization Process. Org. Lett. 2007, 9, 5425-5428.
10. Guo, L.-N.; Duan, X.-H.; Bi, H.-P.; Liu, X.-Y.; Liang, Y.-M. Palladium-Catalyzed Carboannulation of Propargylic Carbonates and Nucleophiles to 2-Substituted Indenes. J. Org. Chem. 2007, 72, 1538-1540.
9.  Bi, H.-P.; Guo, L.-N.; Duan, X.-H.; Gou, F.-R.; Huang, S.-H.; Liu, X.-Y.; Liang, Y.-M. Highly Regio- and Stereoselective Synthesis of Indenes Derivatives via Electrophilic Cyclization. Org. Lett. 2007, 9, 397-400.
8.  Bi, H.-P.; Liu, X.-Y.; Gou, F.-R.; Guo, L.-N.; Duan, X.-H.; Shu, X.-Z.; Liang, Y.-M. Highly Regioselective Synthesis of Spirocyclic Compounds by a Palladium-Catalyzed Intermolecular Tandem Reaction. Angew. Chem., Int. Ed. 2007, 46, 7068-7071.
7.  Bi, H.-P.; Liu, X.-Y.; Gou, F.-R.; Guo, L.-N.; Duan, X.-H.; Liang Y.-M. Highly Regioselective Synthesis of Indene Derivatives Including an AlleneFunctional Group via Pd/C-Catalyzed Cyclization Reaction in Air. Org. Lett. 2007, 9, 3527-3529.
6.  Shu, X.-Z; Liu, X.-Y.; Xiao, H.-Q.; Ji, K.-G.; Guo, L.-N.; Qi, C.-Z.; Liang, Y.-M. Gold-Catalyzed Tandem Cycloisomerization of Alkynyloxiranes with Nucleophiles: An Efficient Approach to 2,5-Disubstituted Furans. Adv. Synth. Catal. 2007, 349, 2493-2498.
5.  Guo, L.-N.; Duan, X.-H.; Bi, H.-P.; Liu, X.-Y.; Liang, Y.-M. Synthesis of Indenes via Palladium-Catalyzed Carboannulation of Diethyl 2-(2-(1-alkynyl)phenyl)malonate and Organic Halides. J. Org. Chem. 2006, 71, 3325-3327.
4.  Duan, X.-H.; Guo, L.-N.; Bi, H.-P.; Liu, X.-Y.; Liang, Y.-M. Highly Regioselective Synthesis of 2,3-Disubstituted Indenes via a Novel Palladium-catalyzed Cyclization Reaction of Propargylic Carbonates with Carbon Nucleophiles. Org. Lett. 2006, 8, 5777-5780.
3.  Duan, X.-H.; Guo, L.-N.; Bi, H.-P.; Liu, X.-Y.; Liang, Y.-M. Synthesis of 2-Substituted 3-Aroylindenes via Palladium-Catalyzed Carbonylative Cyclization of Diethyl 2-(2-(1-Alkynyl)phenyl)malonates with Aryl Halides. Org. Lett. 2006, 8, 3053-3056. 
2  Fan, M.-J.; Guo, L.-N.; Liu, X.-Y.; Liu, W.-M.; Liang, Y.-M. A Mild, Convenient and Efficient Singe-Step Method for the Synthesis of Polysubstituted Furans via Ammonium Ylide Routes. Synthesis. 2005, 391-396.
1.  Duan, X.-H.; Liu, X.-Y.; Guo, L.-N.; Liao, M.-C.; Liu, W.-M.; Liang, Y.-M. Palladium-Catalyzed One-Pot Synthesis of Highly Substituted Furans by a Three-Component Annulation Reaction. J. Org. Chem. 2005, 70, 6980-6983.