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1. 含氟硅功能高分子材料、结构可控杂化材料及其自组装高性能涂膜材料
Fluorin/silicon-containing functional copolymers, structure-controllable hybrids and their self-assembly behavior for high performance coatings
1) Fluorinated acrylic copolymers (FACs) has become a focused point in high-performance coating materials
due to their excellent surface properties of fluorine-containing polymer and favorable adhesive strength to the
substrate of acrylate polymer. The low free energy surface of FACs could be obtained by controlling the surface
chemical composition and by the self-assembly behavior. The aim of research is to synthesize FACs with core-
shell structure by emulsion and block structure by ATRP or RATF with well-defined chemical structure and tailored properties, and to investigate their possible self-assembly behavior in film-formation.
2) The researched copolymer/SiO2 nanohybrids are made of fluorinated copolymers (FPs) or silicon-contained
copolymers (SCPs) and SiO2. FPs/SiO2 or SCPs/SiO2 film in micro/nano hierarchical morphology (high roughness)
and self-migration into top surface of fluorinated groups or silicon-contained groups (low surface free energy) have
make it possible to obtain excellent water and oil repellence and the strong adhesion to the substrate. The aim is to investigate the hydrophobic and adhesive properties of FPs/SiO2 or SCPs/SiO2 nanohybrids synthesized by ATRP/
sol-gel and SI-ATRPATRP techniques, to regulate the distribution of aggregated micelles by self-assemble behavior
as the micro/nano hierarchical morphology of film surface.
2. 复杂体系及天然高分子化合物的识别与检测分析
The characterization of natural polymeric compounds and complex system
Normally, the polychromy is made of pigments and natural polymer as binding medium. The binding medium
plays a key role in the polychromy for fixing the pigments onto the substrate supporter to form the painting layers.
However, the binding medium is easy to be deteriorated with time to cause the damage or extinction of the precious polychromic artworks. But the preciousness and non-reproducibility of ancient polychromy, and the lack of targeted
analytical methods, the limitation of pertinence identification system and standard references, have made the identification
of binding medium and pigments very challengeable. Therefore, it is necessary to improve the effective and feasible
analytical methods and techniques. The study aims to research the nondestructive and in-situ detecting techniques, the
suitable and accurately spectrum database and microanalysis recognition system. The research is focused on：1).
Establishing the targeted analytical methods and the spectrum database by ATR-FTIR, RS and XRF nondestructive techniques for
recognizing the pigment and binding medium; 2). Developing the microanalysis methods and recognition system for identification of binding medium by GC/MS and Py-GC/MS.
3. 文化遗产保护研究
Preservation of cultural heritage
The aim of this field is to preserve the nation’s heritage for future generations through innovative or modern analytical methods and programs.
1) Identifying materials by modern analytical methods
2) Recognizing ancient techniques
3) Fabricating and evaluating the protective materials
(创新港)
