Publications

List of Publications

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[53] Total Synthesis of Prostratin, a Bioactive Tigliane Diterpenoid: Access to Multi-Stereocenter Cyclohexanes from a Phenol

  • Guanghu Tong, Z
  • hengwei Ding, 
  • Zhi Liu, 
  • You-Song Ding, 
  • Liang Xu, 
  • Hailong Zhang, 
  • Pengfei Li*

https://doi.org/10.1021/acs.joc.0c00022

[52] Novel Chiral Ligands‐Enabled Transition‐Metal‐Catalyzed Asymmetric C–H Borylation.

Miao Zhan, Peidong Song, Jiao Jiao,* Pengfei Li,* Chin. J. Chem. 202038,

https://doi.org/10.1002/cjoc.202000023

[51] A unified approach for divergent synthesis of contiguous stereodiads employing a small boronyl group.

Miao Zhan, Zhengwei Ding, Shaozhi Du, Haohua Chen, Chao Feng, Ming Xu, Zhi Liu, Mengxi Zhang, Chao Wu, Yu Lan & Pengfei Li.  Nat. Commun. 2020,11:792.

https://doi.org/10.1038/s41467-020-14592-7

[50] Recent Advances in Continuous-Flow Enantioselective Catalysis. 

Tao Yu, Zhengwei Ding, Wenzheng Nie,Jiao Jiao,* Hailong Zhang, Qian Zhang, Chao Xue, Xinhua Duan, Yoichi M. A. Yamada, Pengfei Li* . Chem. -Eur. J. ASAP

https://doi.org/10.1002/chem.201905151

 

[49] The Marriage of Carborane with Chalcogen Atoms: Nonconjugation, σ−π Conjugation, and Intramolecular Charge Transfer.

Xiaodong Yang, BingjieZhang, Sikun Zhang,Guoping Li, Letian Xu, Zhijun Wang, Pengfei Li,Yanfeng Zhang, Zishun Liu, Gang He*Org. Lett. 2019, 21, 20, 8285-8289.(cover paper

https://doi.org/10.1021/acs.orglett.9b03047

 

[48] Copper-catalyzed borylation of cycloalkylsilyl peroxides via radical C–C bond cleavage. 

,  Org. Chem. Frontiers 2019, 6 ,2932  

DOI: 10.1039/c9qo00472f

 

[47] Photo-controlled release of metal ions using triazoline-containing amphiphilic copolymers.

Xiaoying Xu, Qian Zhang, * Kang Liu, Nailiang Liu, Ying Han,* Weixing Chen, Chao Xie, Pengfei Li  and Jie He Polym. Chem., 2019, 10, 3585–3596.(back cover article)

DOI:10.1039/C9PY00406H

 

[46] Z-bpy, a New C2-Symmetric Bipyridine Ligand and ts Application in Enantioselective Copper(I)-Catalyzed Cyclopropanation of Olefins.

Yizhao Ouyang, Miao Zhan, Jing Zhou,Jiao Jiao, Hao Hu, Yoichi M. A. Yamada,* Pengfei Li,* Chin. J. Chem. 201937, 807-810.

DOI: 10.1002/cjoc.201900141

 

[45] NNB-Type Tridentate Boryl Ligands Enabling a Highly Active Iridium Catalyst for C–H Borylation.

Siyi Ding, Linghua Wang, Zongcheng Miao,* Pengfei Li,* Molecules 2019, 24, 1434.

DOI:10.3390/molecules24071434

 
 

[44] Synthesis of Aryl Trimethylstannane via BF3·OEt2-mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature.

Shuai Mao, Zhengkai Chen, Lu Wang, Daulat Bikram Khadka, Minhang Xin, Pengfei Li,* San-Qi Zhang,*J. Org. Chem. 2019, 84, 463-471.

DOI: 10.1021/acs.joc.8b02766

 

2018
 

[43] Total synthesis of (±)-prostratin.

Guanghu Tong, Zhi Liu, Pengfei Li,* Chem 2018 , 12, 2944-2954

https://doi.org/10.1016

 

2017

[42] Sulfur-Directed Ligand-Free C-H Borylation by Iridium Catalysis.

Li Liu, Guanghui Wang, Jiao Jiao, Pengfei Li,*  Org. Lett. 2017, 19, 6132-6135

DOI: 10.1021/acs.orglett.7b03008

 

[41] Recent Advances in Catalytic C-H Borylation Reaction.

Liang Xu, Guanghui Wang, Shuai Zhang, Hong Wang, Linghua Wang, Li Liu, Jiao Jiao, Pengfei Li,* Tetrahedron  2017,73, 7123-7157 

https://doi.org/10.1016/j.tet.2017.11.005

 

[40] Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation.

Hong Wang, Guanghui Wang, Pengfei Li,* Org. Chem. Frontiers 20174, 1943-1946.

DOI: 10.1039/C7QO00340D

[39] Recent Advances in Transition-Metal-Free Aryl C-B Bond Foemation.

Kai Chen, Linghua Wang, Meng Ge*, Pengfei Li,* Synthesis 2017 49(21): 4719-4730.

www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0036-1590913

[38] Decarboxylative Borylation of Aliphatic Esters under Visible-Light Photoredox Conditions.

Dawei Hu, Linghua Wang, Pengfei Li,* Org. Lett. 2017, 19, 2770-2773.

scifinder.cas.org/scifinder/view/scifinder/scifinderExplore.jsf

[37]  Electrophilicity and Nucleophilicity of Boryl Radicals.

Chao Wu, Xiufang Hou, Yuheng Zheng, Pengfei Li, Dongmei Lu,* J. Org. Chem. 2017, 82, 2898-2905.

https://doi.org/10.1021/acs.joc.6b02849

[36] Soft-nanocoupling between silica and gold nanoparticles based on block copolymer.

Qian Zhang,* Shuhuan Yang, Tingting Zhu, Jung Kwon Oh, Pengfei LiReactive and Functional Polymers, 2017, 110, 30-37.

DOI:dx.doi.org/10.1016/j.reactfunctpolym.2016.10.012

 

[35]  N,B-Bidentate Boryl Ligand-Supported Iridium Catalyst  for Efficient Functional Group-Directed C-H Borylation.

Guanghui Wang, Li Liu, Hong Wang, You-Song Ding, Jing Zhou, Shuai Mao, Pengfei Li,* J. Am. Chem. Soc. 2017,139, 1, 91-94. 

DOI: dx.doi.org/10.1021/jacs.6b11867.

 

 2016

[34] Polyaddition of Azide-Containing Norbornene-Based Monomer through Strain-Promoted 1,3-Dipolar Cycloaddition Reaction.

Xiaojuan Zhang, Qian Zhang,* Yuzhen Wu, Chao Feng, Chao Xie, Xiaodong Fan, Pengfei Li,  Macromol. Rapid. Commun. 2016, 37, 1311 (Cover article).

 

           

[33]  Metal-free Borylation of Electron-Rich Aryl(pseudo)halides under Continuous-Flow Conditions.

Kai Chen, Man Sing Cheung, Zhenyang Lin,* Pengfei Li,* Org. Chem. Frontiers 2016, 3, 875-879. (Hot paper)

https://doi.org/10.1039/C6QO00109B

[32] Synthesis of Aryl Trimethylstannanes from Aryl Halides: An Efficient Photochemical Method.

Kai Chen, Pei He, Shuai Zhang, Pengfei Li,* Chem. Commun. 2016, 52, 9125-9128.

DOI: 10.1039/C6CC01135G.

[31] Efficient Metal-Free Photochemical Borylation of Aryl Halides under Batch and Continuous-Flow Conditions,

Kai Chen, Shuai Zhang, Pei He, Pengfei Li,* Chem. Sci. 2016, 7, 3676-3680. 

DOI: 10.1039/c5sc04521e.

[30] Copper-Catalyzed Boron-Selective C(sp2)−C(sp3) Oxidative Cross-Coupling of Arylboronic Acids and Alkyltrifluoroborates Involving a Single-Electron Transmetalation Process.

Siyi Ding, Liang Xu, Pengfei Li,* ACS Catal. 2016, 6, 1329-1333.

DOI:10.1021/acscatal.5b02524

 

[29] Phosphonated homopolymers and copolymers via ring opening metathesis polymerization: Tg tuning, flame resistance, and photolithography.

Xiaojuan Zhang, Qian Zhang,* Chao Xie, Aiting Gao, Zheng Chang, Jung Kwon Oh, Peng Yang, Pengfei Li,* J. Polymer Sci. Part A: Polymer Chem. 201554, 1396-1408.

DOI: 10.1002/pola.27990.

[28]  Free Radical Nano Scavenger Based on Amphiphilic Novolacs.

Yue Wang, Qian Zhang,* Chao Xie, Xin Zhao, Jinfen Niu, Jie Zhao, Jung Kwon Oh, Peng Li, Pengfei Li,* RSC Adv. 2015, 5, 95666-95673.

DOI:10.1039/c5RA20440B.

 

 2015

[27]  Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules.

Liang Xu, Shuai Zhang, Pengfei Li,* Chem. Soc. Rev. 2015, 44, 8765-8942.

DOI:10.1039/c5cs00338e. 

 

[26] Double N,B-type Bidentate Boryl Ligands Enabling a Highly Active Iridium Catalyst for C-H Borylation.

Guanghui Wang, Liang Xu and Pengfei Li,* J. Am. Chem. Soc. 2015, 137, 8058-8061.   (These authors contributed equally.)

DOI: 10.1021/jacs.5b05252. 

[25]  N-B dative bond-tethered exo-selective intramolecular Diels-Alder reaction.

Chao Feng, Hong Wang, Liang Xu and Pengfei Li,* Org. Biomol. Chem. 2015, 26, 7136-7139.

DOI: 10.1039/c5ob00917k.

  

[24] Synthesis of Silafluorenes and Silaindenes via Silyl Radicals from Arylhydrosilanes: Intramolecular Cyclization and Intermolecular Annulation with Alkynes.

Liang Xu, Shuai Zhang, Pengfei Li,* Org. Chem. Front. 2015, 2, 459-463 (Inside front cover article)

https://doi.org/10.1039/C5QO00012B

[23] Direct Introduction of a Naphthalene-1,8-diamino Boryl [B(dan)] Group by a Pd-Catalyzed Selective Boryl Transfer Reaction.

Liang Xu, Pengfei Li,* Chem. Commun. 2015, 51, 5656-5659.

https://doi.org/10.1039/C5CC00231A

[22]  A Uniformly Porous 2D CN (1:1) Network Predicted by First-Principles Calculations.

Zhengzheng Chen, Pengfei Li,* Chao Wu,* RSC Adv. 2015, 5, 11791-11796.

https://doi.org/10.1039/C4RA15322G

 

 

2014

 

[21] Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki-Miyaura Coupling.

Liang Xu, Pengfei Li,* Synlett 2014, 25, 1799-1802. (Invited SYNPACTS paper)

DOI: 10.1055/s-0033-1339114

 

[20]  Stereocontrolled Construction of the Tricyclic Framework of Tiglianes and Daphnanes by an Oxidative Dearomatization Approach.

Guanghu Tong, Zhi Liu, Pengfei Li,*  Org. Lett. 2014, 16, 2288-2291.

https://doi.org/10.1021/ol5008263

 

[19]  3-Center-5-Electron Boryl Radicals with σ0π1 Ground State Electronic Structure.

Dongmei Lu,* Chao Wu, Pengfei Li,* Org. Lett. 2014, 16, 1486-1489.

https://doi.org/10.1021/ol500296a

 

[18]  Site-differentiated Polyboron Arenes Prepared by Direct C-H Borylation and Their Highly Selective Suzuki-Miyaura Cross-Coupling Reactions.

Liang Xu, Siyi Ding, Pengfei Li,*  Angew. Chem. Int. Ed. 2014, 53, 1822-1826. (†These authors contributed equally.)

https://doi.org/10.1002/anie.201309546

Highlighted by SYNPACTS: Synlett, 2014, 1799-1802.

Highlighted by Chinese J. Org. Chem. 2014, 34, 836.

And Xi’an Jiaotong University web news.

 

[17] Synergistic Effects of Lewis Bases and Substituents on the Electronic Structure and Reactivity of Boryl Radicals.

Dongmei Lu,* Chao Wu, Pengfei Li,*  Chem. Eur. J. 2014, 20, 1630-1637.

https://doi.org/10.1002/chem.201303705

 

 

2013

 

[16] Copper-Catalyzed Trifluoromethylation-Triggered Neophyl-Type Rearrangement of α,α-Diaryl Allylic Alcohols.

Xiaowu Liu, Fei Xiong, Xuanping Huang, Liang Xu, Pengfei Li,* and Xiaoxing Wu,*  Angew. Chem. Int. Ed. 2013, 52, 6962-6966. 

https://doi.org/10.1002/anie.201302673 

Highlighted by SYNPACTS: Synlett, 2013, 24, 1882-1886.

Highlighted by Chinese J. Org. Chem. 2013, 33, 1850.

 

[15]  A Microfluidic System for the Continuous Recycling of Unmodified Homogeneous Palladium Catalysts via Liquid-Liquid Phase Separation.

Pengfei Li,* Jason S. Moore, Klavs F. Jensen,* ChemCatChem 2013, 5, 1729-1733.

https://doi.org/10.1002/cctc.201300054 

 

[14]  Modular Total Synthesis of Rhizopodin: A Highly Potent G-Actin Dimerizing Macrolide.

uel Kretschmer, Michael Dieckmann, Pengfei Li, Sven Rudolph, Daniel Herkommer, Johannes Troendlin, Dirk Menche,* Chem. Eur. J. 2013, 19, 15993-16018.

https://doi.org/10.1002/chem.201302197

 

 

2012

 

[13]  Total Synthesis of Rhizopodin

Michael Dieckmann, Manuel Kretschmer, Pengfei Li, Sven Rudolph, Daniel Herkommer, Dirk Menche, Angew. Chem. Int. Ed. 2012, 51, 5667-5670.

https://doi.org/10.1002/anie.201201946

[12] Continuous-Flow Synthesis of 3,3-Disubstituted Oxindoles by a Palladium-Catalyzed a-Arylation/Alkylation Sequence.

Pengfei Li, Stephen L. Buchwald,  Angew. Chem. Int. Ed. 2011, 50, 6396-6400.

https://doi.org/10.1002/anie.201102401

 

[11]  Concise Synthesis of Tetrahydropyrans by a Tandem Oxa-Michael/Tsuji-Trost Reaction.

Liang Wang, Pengfei Li, Dirk Menche, Angew. Chem. Int. Ed. 2010, 49, 9270-9273.

https://doi.org/10.1002/anie.201003304

 

[10] Stereoselective Total Synthesis of Etnangien and Etnangien Methyl Ester.

Pengfei Li, Jun Li, Fatih Arikan, Wiebke Ahlbrecht, Michael Dieckmann, Dirk Menche* J. Org. Chem. 2010, 75, 2429-2444.

https://doi.org/10.1021/jo100201f

 

[9] Stereodivergent Synthesis of 1,3-syn- and anti-Tetrahydropyrimidinones.

Michael Morgen, Sebastian Bretzke, Pengfei Li, Dirk Menche,  Org.Lett. 2010, 12, 4494-4497.

https://doi.org/10.1021/ol101755m 

 

8.   Dirk Menche*, Pengfei Li, Herbert Irschik, Design, Synthesis and Biological Evaluation of Simplified Analogues of the RNA Polymerase Inhibitor Etnangien, Bioorg. Med. Chem. Lett. 2010, 20, 939-941.

 

7.   Pengfei Li, Jun Li, Fatih Arikan, Wiebke Ahlbrecht, Michael Dieckmann, Dirk Menche*, Total Synthesi of Etnangien, J. Am. Chem. Soc. 2009, 131, 11678-11679.

 

6.  Jun Li, Pengfei Li, Dirk Menche*, An Efficient Procedure for the Direct Nucleophilic Substitution of the Abiko-Masamune Auxiliary, Synlett 2009, 2417-2420.

5.  pengfei Li, Dirk Menche*, Cycloadditions in the Total Synthesis of Sporolide B, Angew. Chem. Int. Ed. 2009, 48, 5078-5080. 

4.     Peng-Fei Li, Bao-Lei Wang, Ning Ma, Su-Hua Wang, Zheng-Ming Li*, Synthesis and Characterization of New 4-(Substituted pyrimidin-2-yl)-1-(Substituted benzensulfonyl)- semicarbazides, Chinese J. Org. Chem. 2005, 25, 1057-1061.

3.      Peng-Fei Li, Ning Ma, Bao-Lei Wang, Zheng-Ming Li*, Su-Hua Wang, Yong-Hong Li, Synthesis and Herbicidal Activity of New Sulfonylurea Derivatives, Chem. J. Chinese Uni. 2005, 26, 1459-1462.

2.  Peng-Fei Li, Bao-Lei Wang, Ning Ma, Zheng-Ming Li*, Su-Hua Wang, Synthesis of 2-Chlorosulfonylbenzoyl Chloride, Chemical Reagents 2005, 27, 445-445.

1.    Ning Ma, Peng-Fei Li, Yong-Hong Li, Zheng-Ming Li*, Ling-Xiu Wang, Su-Hua Wang, Synthesis and Biological Activity of New Phenylsulfonylurea Derivatives, Chem. J. Chinese Uni. 2004, 25, 2259-2262.

 

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Patents

1. Pengfei Li, Guanghui Wang, Liang Xu, Borane preligands and their applications in preparation of aryl boronates, CN 201510067478.0

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Book Chapters

1. Liang Xu, Shuai Zhang, Pengfei Li, “Di- and Polyboron Compounds: Preparation and Chemoselective Transformations in Boron reagents in synthesis (Edited by Adiel Coca), American Chemical Society, 2016. http://pubs.acs.org/isbn/9780841231832

2. Qian Zhang, Yunyue Jiang, Yue Wang, Peng Li, Xin Zhao, Chao Xie, Jie Zhao, Jinfen Niu, Jung Kwon Oh, and Pengfei Li, New Design of Phenol-containing Polymers as Radical Scavengers” in Free Radicals and Health (Edited by Marianne Rutherford), 2016, Nova Science Publishers.

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