Publications

(1) Hu, M.; Ni, C.; Hu, J.* Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a                   Promoter. J. Am. Chem. Soc. 2012, 134, 15257-15260. (This work has been highlighted in Synfacts 2012, 8(12), 1361.)      

(2) Hu, M.; He, Z.; Gao, B.; Li, L.; Ni, C.; Hu, J.* Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C−F Bond Cleavage. J. Am. Chem. Soc. 2013, 135, 17302-17305. (This work has been highlighted in Synfacts 2014, 10(2), 193.)

(3) Hu, M.; Ni, C.; Li, L.; Han, Y.; Hu, J.* gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors. J. Am. Chem. Soc. 2015, 137, 14496.

(4) Hu, M.; Rong, J.; Miao, W.; Ni, C.; Han, Y.; Hu, J.* Copper-Mediated Trifluoromethylthiolation of α-Diazoesters.

Org. Lett. 2014, 16, 2030. (This work has been highlighted in Synfacts 2014, 10(7), 741.)

(5) Hu, M.; Wang, F.; Zhao, Y.; He, Z.; Zhang, W.; Hu, J.* Difluoro(phenylchal- cogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te). J. Fluorine Chem. 2012, 135, 45.

(6) Hu, M.; Gao, B.; Ni, C.; Zhang, L.; Hu, J.* Investigation on the nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent and in situ generated substoichiometric base. J. Fluorine Chem. 2013, 155, 52.

(7) Hu, M.; Xie, Q.; Li, X.; Ni, C.; Hu, J.* Copper-Mediated Deuterotrifluoromethylation of α Diazo Esters. Chin. J. Chem. 2016, 34, 469.

(8) Ni, C.; Hu, M.; Hu, J.* Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis. Chem. Rev. 2015, 115, 765. (Invited review.)

(9) He, Z.; Luo, T.; Hu, M.; Cao, Y.; Hu, J.* Copper-Catalyzed Di- and Trifluoromethylation of a,b-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations. Angew. Chem., Int. Ed. 2012, 51, 3944. (This work has been highlighted in Synfacts 2012, 8(7), 750.)

(10) He, Z.; Hu, M.; Luo, T.; Li, L.; Hu, J.* Copper-Catalyzed Difluoromethylation of β,γ-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation. Angew. Chem., Int. Ed. 2012, 51, 11545.

(11) Gao, B.; Zhao, Y.; Hu, M.; Ni, C.; Hu, J.* gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2- Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction. Chem.−Eur. J. 2014, 20, 7803.

(12) He, Z.; Zhang, R.; Hu, M.; Li, L.; Ni, C.; Hu, J.* Copper-mediated trifluoromethylation of propiolic acids: facile synthesis of α-trifluoromethyl ketones. Chem. Sci. 2013, 4, 3478.

(13) Li, X.; Zhao, J.; Zhang, L.; Hu, M.; Wang, L.; Hu, J.* Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide.

Org. Lett. 2015, 17, 298.

(14) Li, X.; Zhao, J.; Wang, Y.; Rong, J.; Hu, M.; Chen, D.; Xiao, P.; Ni, C.; Wang, L.; Hu, J.* Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2CH3). Chem.–Asian J. 2016, 11, 1789. 

(15) Li, X.; Zhao, J.; Hu, M.; Chen, D.; Ni, C.; Wang, L.; Hu, J.* Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone. Chem. Commun. 2016, 52, 3657. 

(16) Li, L.; Ni, C.; Xie, Q.; Hu, M.; Wang, F.; Hu, J.* TMSCF3 as a Convenient Source of CF2=CF2 for Pentafluoroethylatio, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation. Angew. Chem., Int. Ed. 2017, 56, 9971. 

 

 

 

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