Group news

2D Materials: One dimensional metallic edges in atomically thin WSe2 induced by air exposure


2018-03-12

Our  paper:

One dimensional metallic edges in atomically thin WSe2 induced by air exposure

has been published on 2D Materials.

http://iopscience.iop.org/article/10.1088/2053-1583/aab0cd/meta 

 

Transition metal dichalcogenides are a unique class of layered two-dimensional (2D) crystals with extensive promising applications. Tuning the electronic properties of low-dimensional materials is vital for engineering new functionalities. Surface oxidation is of particular interest because it is a relatively simple method of functionalization. By means of scanning probe microscopy and x-ray photoelectron spectroscopy, we report the observation of metallic edges in atomically thin WSe2 monolayers grown by chemical vapor deposition on epitaxial graphene. Scanning tunneling microscopy shows structural details of WSe2 edges and scanning tunneling spectroscopy reveals the metallic nature of the oxidized edges. Photoemission demonstrates that the formation of metallic sub-stoichiometric tungsten oxide (WO2.7) is responsible for the high conductivity measured along the edges. Ab initio calculations validate the susceptibility of WSe2 nanoribbon edges to oxidation. The zigzag terminated edge exhibits metallic behavior prior the air-exposure and remains metallic after oxidation. Comprehending and exploiting this property opens a new opportunity for application in advanced electronic devices.

http://iopscience.iop.org/2053-1583/5/2/025017/downloadHRFigure/figure/tdmaab0cdf02

 

This work was led by Dr. and Prof. in The University of Texas at Dallas. Yi Pan contributed to this project by performing LT STM/STS measurement at 5K, together with Dr. Stefan Fölsch and Prof. Randall Feenstra, in Paul Drude Institute.