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高国新

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所在单位：化学学院

学历：博士研究生毕业

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学位：博士

职称：教授

学科： 材料科学与工程 、 化学

招生学科 化学 、 化学工程与技术 、 材料科学与工程

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中文主页 / 科学研究 / 论文成果

论文成果

Key Issues and Strategies in Aqueous Static Zinc–Halogen Battery Design

发布时间：2026-01-24

影响因子：
29.1
DOI码：
10.1002/adma.202515759
论文名称：
Key Issues and Strategies in Aqueous Static Zinc–Halogen Battery Design
发表刊物：
Advanced Materials
摘要：
Aqueous zinc-halogen batteries have emerged as leading candidates for next-generation energy storage systems, owing to their inherent advantages such as high theoretical energy density, enhanced safety, and cost-effectiveness derived from earth-abundant zinc and halogen elements. However, the practical implementation of halogen cathodes faces major challenges, including intrinsically low electrical conductivity, the pronounced shuttle effect of soluble polyhalide intermediates, severe corrosion, and competing hydrolysis reactions. These issues call for innovative and rational material design strategies across all battery components. Accordingly, realizing practical zinc-halogen batteries requires a comprehensive understanding that bridges fundamental halogen redox chemistry with targeted material engineering solutions. This review systematically examines the crucial connection between the electrochemistry of halogens and the practical design of battery materials in zinc-halogen systems. Key challenges are first addressed, including stabilizing halogen cathodes, managing reactive halogen species, and optimizing cell configurations. Subsequently, recent pivotal strategies are summarized, including the development of advanced halogen host materials, halogen complexing agents, catalysts for halogen electroactivity, multi-electron redox processes, and electrolyte/separator design. Finally, the essential practical considerations that influence achievable energy density are discussed: such as current collector stability, active halogen ratio, and electrolyte weight/cost, which are critical for realistic performance evaluation and the commercialization of zinc-halogen battery technologies.
合写作者：
高国新,肖春辉
第一作者：
赵洪洋
论文类型：
期刊论文
通讯作者：
丁书江
论文编号：
e15759
学科门类：
工学
一级学科：
材料科学与工程
文献类型：
J
卷号：
38
期号：
29
页面范围：
e15759
ISSN号：
1521-4095
是否译文：
否
发表时间：
2025-11-10
收录刊物：
SCI、SCI
发布期刊链接：
https://advanced.onlinelibrary.wiley.com/doi/epdf/10.1002/adma.202515759?getft_integrator=clarivate&src=getftr&utm_source=clarivate

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