发表文章 - 苏 亚琼
论文标题 | Current‐density regulating lithium metal directional deposition for long cycle‐life Li metal batteries |
作者 | Heng Mao, Wei Yu, Zhuanyun Cai, Guixian Liu, Limin Liu, Rui Wen, Yaqiong Su, Huari Kou, Kai Xi, Benqiang Li, Zhao Hongyang, Xinyu Da, Hu Wu, Wei Yan, Shujiang Ding |
发表/完成日期 | 2021-06-06 |
期刊名称 | Angewandte Chemie International Edition |
期卷 | |
相关文章 | |
论文简介 | Uncontrolled dendrite formation in the high energy density of lithium (Li) metal batteries (LMBs) may pose serious safety risks. While numerous studies have attempted to protect separators, these proposed methods fail to effectively inhibit upward dendrite growth that punctures through the separator. Here, we introduce a novel ‘orientated‐growth’ strategy that transfers the main depositional interface to the anode/current collector interface from the anode/separator interface. We placed a layer of cellulose/graphene carbon composite aerogel (CCA) between the current collector and the anode (LCL‐bottom). This layer works as a charge organizer; it induces a higher apparent current density and encourages Li to deposit at the anode/current collector interface. Both in situ and ex situ images of the electrode demonstrate that the anode part of the cell has been flipped; with the newly deposited particles facing the … |