Xia-Li Ding published a review on Inorganics. Congratulations!

​​​​​​​

Title:Switching the Local Symmetry from D5h to D4h for Single-Molecule Magnets by Non-Coordinating Solvents
Xia-Li Ding, Qian-Cheng Luo, Yuan-Qi Zhai, Qian Zhang*, Lei Tian, Xinliang Zhang, Chao Ke, Xu-Feng Zhang, Yi Lv and Yan-Zhen Zheng*

亮点：观察到溶剂效应对两种单分子磁体性能的影响。四氢呋喃和甲苯溶剂可以分别在[Dy(O^tBu)₂(4-PhPy)₅]BPh₄ 1和Na{[Dy(O^tBu)₂(4-PhPy)₄][BPh4]2hf·hex 2中将赤道配位的4-苯基吡啶（4-PhPy）分子从五个切换到四个。这种交替显著改变了D_5h和D_4h中Dy（III）中心的局部配位对称性。磁学研究表明，2的磁各向异性能垒高于1，而由于对称效应，阻塞温度的关系正好相反。静电势的计算成功地解释了溶剂对分子结构变化的驱动力，证实了通过不同溶剂调节SMMs性能的可行性。

Inorganics 2021, 9(64). Link.