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李洋

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所在单位:化学学院
学历:硕博连读
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性别:男
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学位:博士
职称:副教授
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祝贺石岩同学研究工作被J. Org. Chem. 接收!
发布时间:2023-06-21    点击次数:

发布时间:2023-06-21

文章标题:祝贺石岩同学研究工作被J. Org. Chem. 接收!

内容:

祝贺石岩同学研究工作被J. Org. Chem. 接收!

 

 

A highly efficient iodine anion catalyzed cross-dehydrogenative aromatization of cyclohexenones with amines has been developed under metal-free conditions, which affords aromatic amines in good to excellent yields with a broad substrate scope. Meanwhile, this reaction provides a new method for the construction of C(sp2)–N bonds and also a new strategy for slow generation of oxidants or electrophiles via in situ dehalogenation. Moreover, this protocol affords a rapid and concise approach to chiral NOBIN derivatives. (https://doi.org/10.1021/acs.joc.3c00860)