Reaction mechanism of borane/oxygen radical initiators during the polymerization of fluoromonomers
发布时间：2025-04-30
点击次数：
- 发布时间：
- 2025-04-30
- 论文名称：
- Reaction mechanism of borane/oxygen radical initiators during the polymerization of fluoromonomers
- 发表刊物：
- Macromolecules
- 摘要：
- In summary, the combined information from oxidation adducts of two related boranes (triethylborane and diethyl-methoxylborane) and the polymer chain end structure presents a complete picture of oxidation and the initiation mechanism of broane/oxygen-mediated radical polymerization of fluo-romonomers at ambient temperature. This borane/oxygen initia-tor offers a safe and effective route to prepare fluoropolymers with high molecular weights and high purities. It also provides the control of polymer chain end structure by initiator.
- 合写作者：
- Zhicheng Zhang; T.C. Mike Chung
- 卷号：
- Volume: 39 Issue: 16
- 页面范围：
- 5187-5189
- 是否译文：
- 否
- 发表时间：
- 2006-06-29