Publications
48. Jing Wang, Zenghui Li, Kaixing Gu, Changyuan Xu, Jie Xiong, Tian Han, Ling Yue, and Bin Rao*. "Air-Stable and Luminescent Trityls via Methoxy Modification", Org. Lett. 2026, 28(1), 360–365. link
47. Ya-Wei Geng, Jin-Hui Hu, Xiao-Qin Wang, Yulu Liang, Tian Han* and Peng Cheng*. "Utilizing a Bulky Ligand to Regulate Orbach, Raman, and QTM Relaxation Processes in a Series of Oh-Type Dy(III)-Based Single-Molecule Magnets", SmartMat. 2026, 7(3), e70087. link
46. Ya-Wei Geng, Tong Guo, Xiao-Qin Wang, Tian Han*. "Enhanced Magnetocaloric Effect and Single-Molecule Magnet Behavior in a Series of Sulfur-Containing Ligand-Based Ln9 Clusters (Ln = Gd, Tb, and Dy)", Magnetochemistry 2025, 11(9), 70. (invited) link
该工作被选为期刊封面，封面链接 http://www.mdpi.com/2312-7481/11/9
45. Xiao-Qin Wang, Ya-Wei Geng, Zhimo Wang, Changjian Xie, Tian Han*, and Peng Cheng*. "Two-Dimensional Metal–Organic Framework with High-Performance Single-Molecule Magnets as Nodes Showing Magnetic Coercivity Photomodulation", J. Am. Chem. Soc. 2025, 147, 18044−18053. link
44. Zenghui Li, Xiaoyang Liu, Qidi Bao, Jing Wang, Xu Liu, Honghong Gong, Tian Han, Chao Feng, Dongmei Lu, Ling Yue, Chao Wu, Gang He*, Yuanting Su*, Bin Rao*. "The SUMO (Singly Unoccupied Molecular Orbital)-LUMO (Lowest Unoccupied Molecular Orbital) Inversion Radicals", J. Am. Chem. Soc. 2025, 147, 1452–1457. link
43. Caihong Fan, Kaipeng Bai, Qiancheng Luo, Tian Han*, Chang Huang, Yanzhen Zheng, Weipeng Chen*. "A New Family of SO42–-Templated 3d-4f High-Nuclearity Clusters: Syntheses, Structures, and Magnetic Properties", Chin. J. Chem. 2024, 42, 2438–2444. link
42. Fang-Hua Zhao*, Zi-Hao Zhao, Yu-Shuo Li, Rui Feng, Tian Han, Yuan-Chun He, Zhong-Lin Li*. "Two diverse 3D 6-connected Cd(II)/Co(II) MOFs based on binuclear clusters as fluorescence sensors for detection of Fe3+, Cr2O72− and nitrobenzene", J Mol Struct. 2023, 1298, 137051. link
41. Jiao Jiao, Pei He, Tilong Yang, Tingwei Zhang, Linghua Wang, Tian Han, Yong Nie, Zhenyang Lin, Pengfei Li*. "Asymmetric synthesis of metallacarboranes using a traceless chiral auxiliary", Org. Chem. Front. 2023, 10, 5965–5970. link
40. Yulong Wang, Shenyu Shen, Chonglong He, Youkang Zhou, Keyuan Zhang, Bin Rao, Tian Han, Yaqiong Su, Xin-Hua Duan, Le Liu*. "Cu(ii)-mediated direct intramolecular cyclopropanation of distal olefinic acetate: access to cyclopropane-fused γ-lactones", Chem. Sci. 2023, 14, 6663–6668. link
39. Tian Han*, Xiao-Qin Wang, Tong Guo, Hong-Sheng Cao, Wei-Peng Chen, Ling He. "Modulation of the magnetic dynamics in two air-stable sulfurligated dysprosium complexes via polymerization", Dalton Trans. 2023, 52, 7551–7557. link
38. Tian Han, You-Song Ding, Marcus J. Giansiracusa, Nicholas F. Chilton, Richard E. P. Winpenny, Yan-Zhen Zheng*. "Determinative Effect of Axial Linearity on Single-Molecule Magnet Performance in Dinuclear Dysprosium Complexes", Chem. Eur. J. 2023, 29, e202300256. link
37. Tian Han*, You-Song Ding. “A bis(silyldiamido) dysprosium single-molecule magnet”, Inorg. Chem. Front. 2023, 10, 1803–1808. link
该工作被Frontiers Journals报道，报道链接 https://mp.weixin.qq.com/s/eGwC1HFHeBmZdNhnotLZlw
36. Tian Han*, Xiao-Qin Wang, Yi-Chao Chai, Yan-Zhen Zheng*. "Slow Relaxation of Magnetization in a p‑Semiquinone Radical-Bridged Dysprosium Complex", Cryst. Growth Des. 2023, 23, 24–30. link
35. Yuan-Qi Zhai, Ning Ge, Zi-Han Li, Wei-Peng Chen, Tian Han, Zhong-Wen Ouyang, Zhenxing Wang*, Yan-Zhen Zheng*. "Magnetic Anisotropy: Structural Correlation of a Series of Chromium(II)−Amidinate Complexes", Inorg. Chem. 2021, 60, 1344–1351. link
34. Weipeng Chen, Tian Han, Yanzhen Zheng*. "Dodecanuclear {Co10Ln2} metallorings", Inorganica Chimica Acta 2021, 516, 120112. link
33. Xia-Li Ding, Yuan-Qi Zhai, Tian Han, Wei-Peng Chen, You-Song Ding, Yan-Zhen Zheng*. "A Local D4h Symmetric Dysprosium(III) Single‐Molecule Magnet with an Energy Barrier Exceeding 2000 K", Chem. Eur. J. 2021, 27, 2623–2627. link
32. Zi-Han Li, Yuan-Qi Zhai, Wei-Peng Chen, Qian-Cheng Luo, Tian Han, Yan-Zhen Zheng*. "Breaking the axiality of pentagonal–bipyramidal dysprosium(III) single-molecule magnets with pyrazolate ligands", Inorg. Chem. Front. 2020, 7, 4367–4376. link
31. Haitao Han, You-Song Ding, Xiaofei Zhu, Tian Han, Yan-Zhen Zheng*, Wuping Liao*. "Constructing [CoII6] hexagon-centered heterometallic {Ln6Co6} (Ln = Y, Eu and Dy) clusters with a calix[8]arene ligand", Inorg. Chem. Front. 2020, 7, 4070–4076. link
30. Bo-Kai Ling, Junhao Li, Yuan-Qi Zhai, Hung-Kai Hsu, Yi-Tsu Chan, WeiPeng Chen, Tian Han, Yan-Zhen Zheng*. "Terbium-fluorido cluster: an energy cage for photoluminescence", Chem. Commun. 2020, 56, 9130–9133. link
29. Weipeng Chen, Guojun Zhou, Zhuolun Gou, Sen Wang, Yuanqi Zhai, Tian Han, Jürgen Schnack*, Yanzhen Zheng*. "Hendecanuclear [Cu6Gd5] magnetic cooler with high molecular symmetry of D3h", Chin. Chem. Lett. 2021, 32, 838–841. link
28. Bo-Kai Ling, Yuan-Qi Zhai, Junbo Han, Tian Han*, Yan-Zhen Zheng*. "A stable dysprosium(III) complex with a terminal fluoride ligand showing high resolution luminescence and slow magnetic relaxation", Dalton Trans. 2020, 49, 6969–6973. link
27. Tian Han, Jonatan B. Petersen, Zi-Han Li, Yuan-Qi Zhai, Andreas Kostopoulos, Fabrizio Ortu, Eric J. L. McInnes, Richard E. P. Winpenny*, Yan-Zhen Zheng*. "Dimerized p-Semiquinone Radical Anions Stabilized by a Pair of Rare-Earth Metal Ions", Inorg. Chem. 2020, 59, 7371–7375. link
该工作被X-mol报道，报道链接 https://www.x-mol.com/news/457986
26. Yan Ma, Yuan-Qi Zhai, You-Song Ding, Tian Han*, Yan-Zhen Zheng*. “Understanding a pentagonal-bipyramidal holmium(III) complex with a record energy barrierfor magnetisation reversal”, Chem. Commun. 2020, 56, 3979–3982. link
25. Tian Han, Marcus J. Giansiracusa, Zi-Han Li, You-Song Ding, Nicholas F. Chilton, Richard E. P. Winpenny, Yan-Zhen Zheng*. “Exchange-Biasing in a Dinuclear Dysprosium(III) Single-Molecule Magnet with a Large Energy Barrier for Magnetization Reversal”, Chem. Eur. J. 2020, 26, 6773–6777. link
该工作被AdvancedScienceNews报道
24. You-Song Ding,‡ Tian Han (equal contribution),‡ Yuan-Qi Zhai, Daniel Reta, Nicholas F. Chilton, Richard E. P. Winpenny*, Yan-Zhen Zheng*. “A Study of Magnetic Relaxation in Dysprosium(III) Single-Molecule Magnets”, Chem. Eur. J. 2020, 26, 5893–5902. link
23. Ke-Xin Yu, You-Song Ding, Yuan-Qi Zhai, Tian Han*, Yan-Zhen Zheng*. “Equatorial Coordination Optimization for Enhanced Axiality of Mononuclear Dy(III) Single-Molecule Magnets”, Dalton Trans. 2020, 49, 3222–3227. link
22. Tian Han, You-Song Ding, Zi-Han Li, Ke-Xin Yu, Yuan-Qi Zhai, Nicholas F. Chilton*, Yan-Zhen Zheng*. “A dichlorido-bridged dinuclear Dy(III) single molecule magnet with an effective energy barrier larger than 600 K”, Chem. Commun. 2019, 55, 7930–7933. link
21. Guo-Jun Zhou, Wei-Peng Chen, Youzhu Yu, Lei Qin, Tian Han,* Yan-Zhen Zheng*. “Filling the Missing Links of M3n Prototype 3d-4f and 4f Cyclic Coordination Cages: Syntheses, Structures, and Magnetic Properties of the Ni10Ln5 and the Er3n Wheels”, Inorg. Chem. 2017, 56, 12821–12829. link
20. Yi-Fei Deng, Tian Han,* Wei Xue, Naoaki Hayashi, Hiroshi Kageyama, Yan-Zhen Zheng*. “An Ising iron(II) chain exhibits a large finite-size energy barrier and “hard” magnetic behaviour”, Dalton Trans. 2017, 46, 1449–1454. link
19. Tao Zhang, Yue-Qiao Hu, Zong-Wen Mo, Pei-Qin Liao, Hiroshi Sakiyama, Tian Han,* Xiao-Ming Chen, Yan-Zhen Zheng*. “A Cobalt(II) Magnetic Metal-Organic Framework with an Effective Kagomé Lattice, Large Surface Area and High Spin-Canted Ordering Temperature”, ACS Appl. Mater. Interfaces. 2017, 9, 38181–38186. link
18. Guo-Jun Zhou, Tian Han, You-Song Ding, Nicholas F. Chilton*, Yan-Zhen Zheng*. Chem. Eur. J. 2017, 23, 15617–15622. link
17. Yi-Fei Deng, Tian Han, Bing Yin*, Yan-Zhen Zheng*. Inorg. Chem. Front. 2017, 4, 1141–1148. link
16. Ju-Fang Hu, Tian Han, Ying-Nan Chi*, Zheng-Guo Lin, Yan-Qing Xu, Song Yang, Ding Wei, Yan-Zhen Zheng, Chang-Wen Hu*. Chem. Commun. 2016, 52, 10846–10849. link
15. Yanyan Wang, Tian Han, You-Song Ding, Zhiping Zheng, Yan-Zhen Zheng*. Dalton Trans. 2016, 45, 1103–1110. link
14. You-Song Ding, Tian Han, Yue-Qiao Hu, Minwei Xu, Sen Yang, Yan-Zhen Zheng*. Inorg. Chem. Front. 2016, 3, 798–807. link
13. Ke-Xin Yu, You-Song Ding, Tian Han, Ji-Dong Leng, Yan-Zhen Zheng*. Inorg. Chem. Front. 2016, 3, 1028–1034. link
12. Teng. Li, Yanyan Wang, Lei Qin, Tian Han, You-Song Ding, Yue-Qiao Hu, Yan-Zhen Zheng*. Dalton Trans. 2016, 45, 10798–10806. link
11. Yi-Fei Deng,‡ Tian Han (equal contribution),‡ Zhengxing Wang, Zhongwen Ouyang, Bing Yin*, Zhiping Zheng, J. Krzystek, Yan-Zhen Zheng*. “Uniaxial Magnetic Anisotropy of Square-Planar Chromium(II) Complexes Revealed by Both Magnetic and HF-EPR Studies”, Chem. Commun. 2015, 51, 17688–17691. link
10. Tian Han, You-Song Ding, Ji-Dong Leng, Zhiping Zheng, Yan-Zhen Zheng*. “Polymeric Perturbation to the Magnetic Relaxations of the C2v-Symmetric [Er(Cp)2(OBu)2]− Anion”, Inorg. Chem. 2015, 54, 4588–4590. link
9. Tian Han, Ji-Dong Leng, You-Song Ding, Yanyan Wang, Zhiping Zheng, Yan-Zhen Zheng*. “Field and dilution effects on the magnetic relaxation behaviours of a 1D dysprosium(III)-carboxylate chain built from chiral ligands”, Dalton Trans. 2015, 44, 13480–13484. link
8. Yuan Zhang, Tian Han, Xiao-Qing Liu, Ao Yu, Peng Cheng*. Inorg. Chem. Commun. 2015, 57, 1–3. link
7. Yuan Jiang, Lei Qin, Guanghua Li, Ghulam Abbas, Yaqun Cao, Gang Wu*, Tian Han, Yan-Zhen Zheng*, Shilun Qiu*. Dalton Trans. 2015, 44, 5205–5210. link
6. Tian Han, Wei Shi*, Zheng Niu, Bo Na, Peng Cheng*. “Magnetic Blocking from Exchange Interaction: Slow Relaxation of the Magnetization and Hysteresis Loop Observed in a Dysprosium–Nitronyl Nitroxide Chain Compound with an Antiferromagnetic Ground State”, Chem. Eur. J. 2013, 19, 994–1001. link
5. Bo Na, Yu-Xia Wang, Tian Han, Wei Shi, Peng Cheng*. Inorg. Chem. Commun. 2013, 35, 19–21. link
4. Tian Han, Wei Shi*, Xiao-Ping Zhang, Lei-Lei Li, Peng Cheng*. “A Family of Binuclear Dysprosium(III)-Radical Compounds with Magnetic Relaxation in ON and OFF States”, Inorg. Chem. 2012, 51, 13009–13016. link
3. Tian Han, Peng Ren, Na Xu*, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan. “Ferro/antiferromagnetic interactions transmitted by double bridged carboxylate groups in 2D mixed-ligand transition metal coordination polymers”, Inorg. Chim. Acta 2012, 387, 212–218. link
2. Huan-Huan Li, Wei Shi*, Na Xu, Zhen-Jie Zhang, Zheng Niu, Tian Han, Peng Cheng*. Cryst. Growth Des. 2012, 12, 2602–2612. link
1. HuanHuan Li, Zheng Niu, Tian Han, ZhenJie Zhang, Wei Shi, Peng Cheng*. Sci. China Chem. 2011, 54, 1423–1429. link
Chapters
1. Tian Han, You-Song Ding, Yan-Zhen Zheng*. “Lanthanide Clusters toward Single-Molecule Magnets”, Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials, Structure and Bonding, Springer, Heidelberg, 2017, 209–314. link
Patents
1. 程鹏, 韩甜, 师唯，一种金属-自由基一维配位聚合物磁性材料及制备和应用，2013. 8，CN201110266913.
2. 程鹏, 韩甜, 师唯，一种金属-自由基配合物型磁性材料及其制备和应用，2015. 1，CN201210584653.
