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祝贺石岩同学研究工作被J. Org. Chem. 接收!
发布者: 李洋 | 2023-06-21 | 153

祝贺石岩同学研究工作被J. Org. Chem. 接收!

 

 

A highly efficient iodine anion catalyzed cross-dehydrogenative aromatization of cyclohexenones with amines has been developed under metal-free conditions, which affords aromatic amines in good to excellent yields with a broad substrate scope. Meanwhile, this reaction provides a new method for the construction of C(sp2)–N bonds and also a new strategy for slow generation of oxidants or electrophiles via in situ dehalogenation. Moreover, this protocol affords a rapid and concise approach to chiral NOBIN derivatives. (https://doi.org/10.1021/acs.joc.3c00860)