目前主要从事含氟聚合物的功能化改性及应用研究，主持国家自然科学基金面上/青年、陕西省自然基金青年项目及企业合作项目8项；近年来在Advanced Materials、Journal of Materials Chemistry A/C、Chemical Engineering Journal、Macromolecules等国际国内知名刊物上发表SCI论文50余篇；荣获陕西省技术发明二等奖1项、发明协会创新创业奖二等奖1项、陕西高等学校科学技术研究优秀成果一等奖及二等奖各1项。
陕西省西安市西安交通大学化学学院化学楼
陕西省西咸新区交大创新港19-5129室
Email: shaobotan.1987@xjtu.edu.cn
2019.05-今 西安交通大学化学学院 副教授
2015.07-2019.05 西安交通大学理学院 讲师
2017.07-2018.07 美国南卡罗来纳大学 访问学者 合作导师：唐传兵教授
2009.09-2015.06 西安交通大学 材料科学与工程 博士（硕博连读） 导师：张志成教授
2005.09-2009.07 西安工程大学 高分子材料与工程 本科
1. 可控自由基聚合方法学
2. 含氟聚合物改性新方法
3. 铁电聚合物
4. 电活性聚合物
欢迎化学、材料等相关专业的同学报考
一、研究生招生专业
应用化学
考试科目：① 101 思想政治理论 ② 201 英语一 ③ 302数学二 ④ 821有机化学
高分子化学与物理
考试科目：① 101 思想政治理论 ② 201 英语一 ③ 723 物理化学 ④ 821 有机化学
二、招收免试研究生基本条件
化学学院2025年招收推荐免试研究生细则：http://chem.xjtu.edu.cn/info/1034/4427.htm
课题组招收推荐免试研究生启示：详细内容请见 PDF文件
(57) Meirong Zhang, Qiuwei Wang, Jingyang Wang, Dong Ma, Bincheng Ren, Honghong Gong, Shaobo Tan, Yunchuan Xie, Zhenxue Liu, Dengfeng Gao*, Zhicheng Zhang*. Crystallization and permittivity engineering with polar electron-deficient molecules for enhanced energy storage in polypropylene capacitor films. Compos. Sci. Technol. 2026. https://doi.org/10.1016/j.compscitech.2026.111727.
(56) Ba Qin, Guotong Ding, Wanli Xing, Xiaoyu Yang, Wenxuan Li, Zhemin Chen, Shaobo Tan*, Xiaoyong Wei*, Zhicheng Zhang*. Quantifying structure-property relationships in ferroelectric polymers toward high-performance soft robots. Adv. Sci. 2026. https://doi.org/10.1002/advs.75884.
(55) Yichun Peng, Rongrui Zhang, Meirong Zhang, Dong Ma, Runze Zhang, Jie Xiong, Tao Lu, Ba Qin, Shaobo Tan*, Qiangzhou Rong*, Zhicheng Zhang*. Surface modification and gradient polarization synergistically enhance the piezoelectric properties of P(VDF-TrFE) for high resolution photoacoustic imaging. ACS Sens. 2026, 11, 5080-5089. https://doi.org/10.1021/acssensors.6c01128.
(54) Xiaoyu Yang, Ba Qin, Jingxiao Zheng, Jie Xiong, Shaobo Tan*, Zhicheng Zhang. Enhanced high-temperature capacitive energy storage in poly(tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride) via chemical grafting modification. ACS Appl. Energy Mater. 2026, 9, 6341-6349. https://doi.org/10.1021/acsaem.6c00547.
(53) Rui Shao, Yichun Peng, Ba Qin, Tao Lu, Zhong Li, Weiwei Zhu, Weimin Xia, Shaobo Tan*, Zhicheng Zhang*. A PVDF-based flexible keyboard device exploiting the piezoelectric effect. IEEE Trans. Dielectr. Electr. Insul. 2026. DOI: 10.1109/TDEI.2026.3681735.
(52) Cheng Yao, Dong Ma, Jingchun Hou, Shaobo Tan, Jie Xiong, Weichen He, Jingqi Zhang, Meirong Zhang*, Changsheng Ji*, Zhicheng Zhang*. Synergistic enhancement of high-temperature stability and energy-storage performance in polypropylene dielectric films via molecular trap engineering. Mater. Horiz. 2026, 13, 3621-3629. https://doi.org/10.1039/D5MH02339D.
(51) Ba Qin, Peng Wang, Wanli Xing, Shaobo Tan*, Xiaoyong Wei*, Zhicheng Zhang*. Electroactive properties of PVDF-based ferroelectric polymers: A review. Macromol. Rapid Commun. 2026, 47, e00683. https://doi.org/10.1002/marc.202500683.
(50) Miao Wang, Jingxiao Zheng, Jie Xiong, Rixian Ding, Shaobo Tan*, Zhicheng Zhang. Tailoring polar groups in ethylene-tetrafluoroethylene copolymer for enhanced dielectric energy storage performance. ACS Appl. Mater. Interfaces. 2026, 18, 5290-5300. https://doi.org/10.1021/acsami.5c21185.
(49) Ba Qin, Guotong Ding, Xiaoyu Yang, Wenxuan Li, Yijin He, Anyi Ren, Wanli Xing, Shaobo Tan*, Xiaoyong Wei*, Zhicheng Zhang*. Ultrahigh piezoelectric coefficients achieved by tailoring the sequence and nano-domain structure of P(VDF-TrFE). Adv. Mater. 2025, 2502708. https://doi.org/10.1002/adma.202502708.
(48) Jie Xiong, Meng Li, Teng Lu, Ting Zhang, Mingyou Hu, Meirong Zhang, Yunchuan Xie*, Shaobo Tan, Honghong Gong*, Zhicheng Zhang*. Excellent high-temperature energy storage performance of polymer dielectrics through the synergistic action of conjugation effect inhibition and dipole modulation. Chem. Eng. J. 2025, 507, 160661. https://doi.org/10.1016/j.cej.2025.160661.
(47) Jie Xiong, Guanxiang Zhang, Shaobo Tan, Honghong Gong*, Yunchuan Xie*, Xiao Zhang, Zhicheng Zhang*. One-step fabricating high energy storage polymer film with wide bandgap and high melting temperature induced by fluorine effect for high temperature capacitors applications with ultra-high efficiency. Mater. Horiz. 2025, 12, 238-245. https://doi.org/10.1039/D4MH01225A.
(46) Chunyu Zhao, Zaozhen He, Ying Zhou, Wei Xiong, Ling He, Youshen Wu, Shaobo Tan, Zhicheng Zhang, Yi Liu, Aizhao Pan*. Homogenous luminescent perovskite-acrylate based films with self-wrinkling patterned surface for flexible full-color backlight display. Appl. Surf. Sci. 2025, 686, 162214. https://doi.org/10.1016/j.apsusc.2024.162214.
(45) Miao Wang, Yijin He, Xiaoyu Yang, Xuhui Hou, Wenxuan Li, Shaobo Tan*, Zhicheng Zhang*. Optimizing thermal and dielectric properties of ethylene-tetrafluoroethylene (ETFE)/h-BN composites via interface engineering: Activation of C-F bonds on ETFE for surface grafting. J. Mater. Chem. A. 2024, 12, 31424-31431. https://doi.org/10.1039/D4TA06110A.
(44) Yijin He, Guanxiang Zhang, Ba Qin, Wenxuan Li, Guansong He, Bofeng Zhu, Xiao Zhang, Shaobo Tan*, Zhicheng Zhang*. Excellent dielectric energy storage performance achieved by synergistically increasing the permittivity and breakdown strength of poly(vinylidene chloride-co-vinyl chloride) with a stabilized conformation. J. Mater. Chem. A. 2024, 12, 21824-21829. https://doi.org/10.1039/D4TA04534C.
(43) Yijin He, Cong Xu, Wenxuan Li, Zhong Wei*, Heyun Wang, Shaobo Tan, Zhicheng Zhang*. Achieving enhanced dielectric and energy storage performance in poly(vinyl chloride-glycidyl methacrylate) through tuning interchain interactions. ACS Appl. Mater. Interfaces. 2024, 16, 26808-26816. https://doi.org/10.1021/acsami.4c05096.
(42) Miao Wang, Mingxin Lei, Xiaoyu Yang, Ling Li, Shaobo Tan*, Hanli Wang*, Zhicheng Zhang*. Tailoring the dielectric performance of poly(vinylidene fluoride-co-tetrafluoroethylene) through chemical grafting via visible-light induced C-F bond activation. ACS Appl. Energy Mater. 2024, 7, 1320-1328. https://doi.org/10.1021/acsaem.3c03013.
(41) Shaobo Tan, Ziting Xi, Xinwei Li, Jie Xiong, Xiao Wang, Zhicheng Zhang*. Improved dielectric tunability in stretched P(VDF-DB). IEEE Trans. Dielectr. Electr. Insul. 2023, 30, 2476-2481. DOI: 10.1109/TDEI.2023.3316636.
(40) Leipeng Liu*, Haochen Yun, Kangning Zhang, Zhe Ji, Jinru Liu, Shenghua Lv, Shaobo Tan*. Improved electromechanical properties of polydimethylsiloxane composites with sandwich structured Al(OH)3@GO nanosheets. Polym. Compos. 2023, 44, 4905-4914. https://doi.org/10.1002/pc.27452.
(39) Yijin He, Bofeng Zhu, Shaobo Tan, Zhenxue Liu, Xiao Zhang*, Zhicheng Zhang*. Improving the energy storage performance of a chlorinated poly(vinyl chloride) film at elevated electric field and temperature via a simple annealing process. ACS Appl. Energy Mater. 2023, 6, 5407-5415. https://doi.org/10.1021/acsaem.3c00518.
(38) Honghong Gong, Ying Zhang, Yipin Cheng, Qinglong Ji, Mengdi Sun, Shaobo Tan, Zicai Zhu, Zhicheng Zhang*. Integrating deformation technology with visualization technology: A new roadmap for the future of smart actuator. React. Funct. Polym. 2023, 186, 105573. https://doi.org/10.1016/j.reactfunctpolym.2023.105573.
(37) Meirong Zhang, Xiao Zhang, Bofeng Zhu, Shaobo Tan, Honghong Gong, Xiaoyong Wei*, Zhicheng Zhang*. High energy density and low energy loss inspired by inserting charge traps in all organic dielectric materials. J. Mater. Chem. A. 2022, 10, 16258-16267. https://doi.org/10.1039/D2TA03884F.
(36) Zhong Li, Xing Fan, Jia Yi, Shaobo Tan, Zhicheng Zhang*, Tao Lu, Linjun Zhang, Weiwei Zhu. Outstanding piezoelectric sensitivity of Poly(vinylidene-trifluoroethylene) for acceleration sensor application. IEEE Trans. Dielectr. Electr. Insul. 2022, 29, 808-814. DOI: 10.1109/TDEI.2022.3157923.
(35) Miao Wang, Mingxin Lei, Shaobo Tan*, Zhicheng Zhang*. Grafting modification of poly(vinylidene fluoride-trifluoroethylene) via visible-light mediated C-F bond activation. Macromol. Chem. Phys. 2022, 223, 2200041. https://doi.org/10.1002/macp.202200041.
(34) Qizheng Li, Yijin He, Shaobo Tan, Bofeng Zhu, Xiao Zhang*, Zhicheng Zhang*. Dielectric elastomer with excellent electromechanical performance by dipole manipulation of Poly(vinyl chloride) for artificial muscles under low driving voltage application. Chem. Eng. J. 2022, 441, 136000. https://doi.org/10.1016/j.cej.2022.136000.
(33) Xinwei Li, Shaobo Tan*, Weiwei Zhu, Zhicheng Zhang. Tailoring dielectric performance of P(VDF-CTFE) via incorporating thiophenol as a side chain. React. Funct. Polym. 2022, 170, 105122. https://doi.org/10.1016/j.reactfunctpolym.2021.105122.
(32) Meirong Zhang, Shaobo Tan, Jie Xiong, Chao Chen, Ying Zhang, Xiaoyong Wei*, Zhicheng Zhang*. Tailoring dielectric and energy storage performance of PVDF based relaxor ferroelectric with hydrogen bond. ACS Appl. Energy Mater. 2021, 4, 8454-8464. https://doi.org/10.1021/acsaem.1c01658.
(31) Yingdong Duan, Qizheng Li, Biyun Peng, Shaobo Tan*, Zhicheng Zhang. Grafting modification of poly(vinylidene fluoride-hexafluoropropylene) via Cu(0) mediated controlled radical polymerization. React. Funct. Polym. 2021, 164, 104939. https://doi.org/10.1016/j.reactfunctpolym.2021.104939.
(30) Biyun Peng, Jian Wang, Meng Li, Miao Wang, Shaobo Tan*, Zhicheng Zhang*. Activation of different C-F bonds in fluoropolymers for Cu(0)-mediated single electron transfer radical polymerization. Polym. Chem. 2021, 12, 3132-3141. https://doi.org/10.1039/D1PY00376C.
(29) Miao Wang, Jiani Liao, Biyun Peng, Ying Zhang, Shaobo Tan*, Zhicheng Zhang. Facile Grafting Modification of Poly(vinylidene fluoride‐co‐trifluoroethylene) Directly from Inner CH=CH Bonds. Macromol. Chem. Phys. 2021, 222, 2100017. https://doi.org/10.1002/macp.202100017.
(28) Qizheng Li, Shaobo Tan, Honghong Gong, Junyong Lu, Wenjing Zhang, Xiao Zhang*, Zhicheng Zhang*. Influence of dipole and intermolecular interaction on the tuning dielectric and energy storage properties of polystyrene-based polymers. Phys. Chem. Chem. Phys. 2021, 23, 3856-3865. https://doi.org/10.1039/D0CP05233G.
(27) Yunchuan Xie, Jian Wang, Shaobo Tan, Biyun Peng, Baobao Qiao, Zhicheng Zhang*, Xingyi Huang*, Heliang Sui*. Improving Energy Storage Density and Efficiency of Polymer Dielectrics by Adding Trace Biomimetic Lysozyme-Modified Boron Nitride. ACS Appl. Energy Mater. 2020, 3, 7952-7963.
https://doi.org/10.1021/acsaem.0c01317.
(26) Xiao Wang, Baobao Qiao, Shaobo Tan, Weiwei Zhu*, Zhicheng Zhang*. Tuning the Ferroelectric Phase Transition of PVDF by Uniaxially Stretching Crosslinked PVDF Films with CF=CH Bonds. J. Mater. Chem. C. 2020, 8, 11426-11440. https://doi.org/10.1039/D0TC02559C.
(25) Jiani Liao, Biyun Peng, Shaobo Tan*, Xin Tian*, Zhicheng Zhang. Grafting PMMA onto P(VDF-TrFE) by C-F Activation via a Cu(0) Mediated Controlled Radical Polymerization Process. Macromol. Rapid Commun. 2020, 41, 1900613. https://doi.org/10.1002/marc.201900613.
(24) Baobao Qiao, Xiao Wang, Shaobo Tan, Weiwei Zhu*, Zhicheng Zhang*. Synergistic Effects of Maxwell Stress and Electrostriction in Electromechanical Properties of Poly(vinylidene fluoride)-Based Ferroelectric Polymers. Macromolecules. 2019, 52, 9000-9011. https://doi.org/10.1021/acs.macromol.9b01580.
(23) Qizheng Li, Jingjing Liu, Xiao Zhang, Shaobo Tan, Junyong Lu, Zhicheng Zhang*. Tuning the dielectric and energy storage properties of polystyrene-based polymer dielectric by manipulating dipoles and their polarizing behavior. Phys. Chem. Chem. Phys. 2019, 21, 15712-15724. https://doi.org/10.1039/C9CP01798D.
(22) Zhicheng Zhang*, Xiao Wang, Shaobo Tan, Qing Wang*. Superior electrostrictive strain achieved under low electric fields in relaxor ferroelectric polymers. J. Mater. Chem. A. 2019, 7, 5201-5208. https://doi.org/10.1039/C8TA11938D.
(21) Shaobo Tan, Ye Sha, Tianyu Zhu, Md Anisur Rahman, Chuanbing Tang*. Photoresponsive supramolecular polymers based on quadruple hydrogen-bonding and a photochromic azobenzene motif. Polym. Chem. 2018, 9, 5395-5401. https://doi.org/10.1039/C8PY01217B.
(20) Ye Sha, Yudi Zhang, Tianyu Zhu, Shaobo Tan, Yujin Cha, Stephen L. Craig*, Chuanbing Tang*. Ring-Closing Metathesis and Ring-Opening Metathesis Polymerization toward Main-Chain Ferrocene-Containing Polymers. Macromolecules. 2018, 51, 9131-9139. https://doi.org/10.1021/acs.macromol.8b02064.
(19) Yanan Zhang, Shaobo Tan, Jian Wang, Xiao Wang, Weiwei Zhu*, Zhicheng Zhang*. Regulating Dielectric and Ferroelectric Properties of Poly(vinylidene fluoride-trifluoroethylene) with Inner CH=CH Bonds. Polymers. 2018, 10, 339. https://doi.org/10.3390/polym10030339.
(18) Shaobo Tan, Dan Li, Yanan Zhang, Zhijing Niu, Zhicheng Zhang*. Base Catalyzed Thiol-Ene Click Chemistry toward Inner -CH=CF- Bonds for Controlled Functionalization of Poly(vinylidene fluoride). Macromol. Chem. Phys. 2018, 219, 1700632. https://doi.org/10.1002/macp.201700632.
(17) Shaobo Tan, Jie Xiong, Yifei Zhao, Jingjing Liu, Zhicheng Zhang*. Synthesis of poly(vinylidene fluoride-co-chlorotrifluoroethylene)-g-poly(methyl methacrylate) with low dielectric loss by photo-induced metal-free ATRP. J. Mater. Chem. C. 2018, 6, 4131-4139. https://doi.org/10.1039/C8TC00781K.
(16) Shaobo Tan, Yifei Zhao, Wanwan Zhang, Pin Gao, Weiwei Zhu*, Zhicheng Zhang*. A light-mediated metal-free atom transfer radical chain transfer reaction for the controlled hydrogenation of poly(vinylidene fluoride-chlorotrifluoroethylene). Polym. Chem. 2018, 9, 221-227. https://doi.org/10.1039/C7PY01870C.
(15) Shaobo Tan, Yanan Zhang, Zhijing Niu, Zhicheng Zhang*. Copper(0) Mediated Single Electron Transfer Controlled Radical Polymerization toward C-F Bonds on Poly(vinylidene fluoride). Macromol. Rapid Commun. 2018, 39, 1700561. https://doi.org/10.1002/marc.201700561.
(14) Xiao Wang, Yanan Zhang, Shaobo Tan, Zhicheng Zhang*. Multiple relaxation in uniaxially stretched P(VDF-TrFE) films after crosslinking. IEEE Trans. Dielectr. Electr. Insul. 2017, 24, 2531-2540. DOI: 10.1109/TDEI.2017.006296.
(13) Wanwan Zhang, Jian Wang, Pin Gao, Shaobo Tan, Weiwei Zhu, Zhicheng Zhang*. Synthesis of poly(vinylidene fluoride-trifluoroethylene) via a controlled silyl radical reduction of poly(vinylidene fluoride-chlorotrifluoroethylene). J. Mater. Chem. C. 2017, 5, 6433-6441. https://doi.org/10.1039/C7TC01051F.
(12) Yanan Zhang, Yifei Zhao, Shaobo Tan, Zhicheng Zhang*. Inserting -CH=CH- into P(VDF-TrFE) by C-F activation mediated with Cu(0) in a controlled atom transfer radical elimination process. Polym. Chem. 2017, 8, 1840-1849. https://doi.org/10.1039/C6PY02119K.
(11) Bei Miao, Jingjing Liu, Xiao Zhang, Junyong Lu, Shaobo Tan, Zhicheng Zhang*. Ferroelectric relaxation dependence of poly(vinylidene fluoride-co-trifluoroethylene) on frequency and temperature after grafting with poly(methyl methacrylate). RSC Adv. 2016, 6, 84426-84438. https://doi.org/10.1039/C6RA17977K.
(10) Honghong Gong, Xiaomeng Zhang, Yanan Zhang, Aqun Zheng, Shaobo Tan, Zhicheng Zhang*. Chemical composition characterization of poly(vinylidene fluoride-chlorotrifluoroethylene)-based copolymers with F-H decoupled 1H NMR. RSC Adv. 2016, 6, 75880-75889. https://doi.org/10.1039/C6RA11757K.
(9) Xin Hu, Shaobo Tan, Guoxin Gao, Yunchuan Xie, Qinzhuo Wang, Na Li, Zhicheng Zhang*. Synthesis of unsaturation containing P(VDF‐co‐TrFE‐co‐CTFE) from P(VDF‐co‐CTFE) in one‐pot catalyzed with Cu(0)‐based single electron transfer living radical polymerization system. J. Polym. Sci. Polym. Chem. 2014, 2, 3429-34401. https://doi.org/10.1002/pola.27410.
(8) Jing Chen, Shaobo Tan, Guoxin Gao, Huayi Li, Zhicheng Zhang*. Synthesis and characterization of thermally self-curable fluoropolymer triggered by TEMPO in one pot for high performance rubber applications. Polym. Chem. 2014, 5, 2130-2141. https://doi.org/10.1039/C3PY01390A.
(7) Fei Wen, Zhuo Xu, Shaobo Tan, Weimin Xia, Xiaoyong Wei, Zhicheng Zhang*. Chemical Bonding Induced Low Dielectric Loss and Low Conductivity in High-K poly (vinylidene fluoride-trifluorethylene)/Graphene Nanosheets Nanocomposites. ACS Appl. Mater. Interfaces. 2013, 5, 9411-9420. https://doi.org/10.1021/am401784p.
(6) Shaobo Tan, Xin Hu, Shujiang Ding, Zhicheng Zhang*, Huayi Li, Lanjun Yang. Significantly improving dielectric and energy storage properties via uniaxially stretching crosslinked P(VDF-co-TrFE) films. J. Mater. Chem. A. 2013, 1, 10353-10361. https://doi.org/10.1039/C3TA11484H.
(5) Shaobo Tan, Junjie Li, Guoxin Gao, Huayi Li, Zhicheng Zhang*. Synthesis of fluoropolymer containing tunable unsaturation by a controlled dehydrochlorination of P(VDF-co-CTFE) and its curing for high performance rubber applications. J. Mater. Chem. 2012, 22, 18496-18505. https://doi.org/10.1039/C2JM33133K.
(4) Junjie Li, Shaobo Tan, Shujiang Ding, Huayi Li, Lanjun Yang, Zhicheng Zhang*. High-field antiferroelectric behaviour and minimized energy loss in poly(vinylidene-co-trifluoroethylene)-graft-poly(ethyl methacrylate) for energy storage application. J. Mater. Chem. 2012, 22, 23468-23476. https://doi.org/10.1039/C2JM35532A.
(3) Shaobo Tan, Erqiang Liu, Qiuping Zhang, Zhicheng Zhang*. Controlled Hydrogenation of P(VDF-co-CTFE) to Prepare P(VDF-co-TrFE-co-CTFE) in the Presence of CuX(X=Cl, Br) Complexes. Chem. Commun. 2011, 47, 4544-4546. https://doi.org/10.1039/C1CC00106J.
(2) Shaobo Tan, Junjie Li, Zhicheng Zhang*. Study of Chain Transfer Reaction to Solvents in the Initiation Stage of Atom Transfer Radical Polymerization. Macromolecules. 2011, 44, 7911-7916. https://doi.org/10.1021/ma201942z.
(1) Shaobo Tan, Qinghao Yang, Zhicheng Zhang*. Synthesis and Characterization of P(VDF-TrFE-CTFE)-g-SPS. Acta Polymerica Sinica. 2010,11,1269-1275.
