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24. Ben He, Sikun Zhang, Yueyan Zhang, Guoping Li, Bingjie Zhang, Wenqiang Ma, Bin Rao, Ruitong Song, Lei Zhang, Yanfeng Zhang and Gang He*. ortho-Terphenylene Viologens with Through-Space Conjugation for Enhanced Photocatalytic Oxidative Coupling and Hydrogen Evolution.  J. Am. Chem. Soc.  2022, xx.

23. Xiaodong Yang, Bingjie Zhang, Yujing Gao, Chenjing Liu, Guoping Li,* Bin Rao, Dake Chu, Ni Yan, Mingming Zhang, and Gang He*. Efficient Photoinduced Electron Transfer from Pyrene-o-Carborane Heterojunction to Selenoviologen for Enhanced Photocatalytic Hydrogen Evolution and Reduction of Alkynes,Adv. Sci. 2021, 2101652

22. Letian Xu,  Kun Zhou,  Xinyu Qiu,  Bin Rao,  Dandan Pei,  Ang Li,  Zhongfu An,  Gang He, Tunable ultralong organic phosphorescence modulated by main-group elements with different Lewis acidity and basicity,  J. Mater .Chem. C  2020, 8, 14740-14747.

21. Ruitong Song, Guoping Li, Yueyan Zhang, Bin Rao, Shanxin Xiong, Gang He*, Novel Electrochromic Materials Based on Chalcogenoviologens for Smart Windows, E-Price Tag and Flexible Display with Improved Reversibility and Stability, Chemical Engineering Journal, 2021, 130057

20. Sikun Zhang, Xiaodong Yang, Xu Liu, Letian Xu, Bin Rao, Ni Yan and Gang He*. Dithienoazaborine derivatives with selective π-conjugated extension via late-stage functionalization J. Mater. Chem. C, 2021, 9, 4053-4061

19. Qiang Zhang, Shujuan Wang, Bin Rao, Xingxing Chen, Li Ma, Chenhui Cui, Qianyun Zhong, Zhen Li, Yilong Cheng and Yanfeng Zhang*, Hindered urea bonds for dynamic polymers: An overview, Reactive and Functional Polymers 2021, 159, 104807.

​​​​​​​18. Wenqiang Ma, Letian Xu, Sikun Zhang, Guoping Li, Tianyu Ma, Bin Rao, Mingming Zhang, and Gang He*, Phosphorescent Bismoviologens for Electrophosphorochromism and Visible Light-Induced Cross-Dehydrogenative CouplingJ. Am. Chem. Soc. 2021, 143, 1590–1597​​​​​​​.

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      (NOTE: * Corresponding Author; # Equal Contribution)

      17. Bin Rao and Rei Kinjo*, Crystalline Boragermenes, Angew. Chem. Int. Ed. 2020, 59, 3147–3150.

16. Bin Rao and Rei Kinjo*, A Cyclic (Alkyl)(boryl)germylene Derived from a Cyclic (Alkyl)(amino)germylene, Angew. Chem.  Int. Ed. 2019, 58, 18150–18153.

15. Bin Rao, Liliang Wang, Rei Kinjo*, Borane-Catalyzed Cross-Metathesis Strategy for Facile Transformation of Cyclic (Alkyl)(Amino)Germylenes, Angew. Chem. Int. Ed. 2019, 58, 231–235.

14.  Bin Rao, Che Chang Chong, Rei Kinjo*, Metal-Free Regio- and Chemoselective Hydroboration of Pyridines Catalyzed by 1,3,2-Diazaphosphenium Triflate, J. Am. Chem. Soc. 2018, 140, 652–656.

13.  Bin Rao, Rei Kinjo*, Boron-Based Catalysts for C−C Bond Formation Reactions, Chem. Asian J. 2018, 1279–1292.

12.  Che Chang Chong(#), Bin Rao(#), Rei Kinjo*, Metal-Free Catalytic Reduction of a,b-Unsaturated Esters by 1,3,2-Diazadiphospholene and Subsequent C–C Coupling with Nitriles, ACS Catal. 2017, 7, 5814–5819.

11.  Che Chang Chong, Bin Rao, Yongxin Li, Rakesh Ganguly, Rei Kinjo*, Bis(N-heterocyclic olefin) Derivative: An Efficient Precursor for Isophosphindolylium Species, Inorg. Chem. 2017, 56, 8608–8614.

10.  Bin Rao, Jinhua Tang, Xiaoming Zeng*, Synthesis of 2-Benzylphenyl Ketones by Aryne Insertion into Unactivated C–C Bonds, Org. Lett. 2016, 18,1678–1681.

9.    Bin Rao, Jinhua Tang, Yu Wei, Xiaoming Zeng*, Ring Expansion via Cleavage of Benzylic C-C Bonds Enabling Direct Synthesis of Medium Ring-fused Benzocarbocycles, Chem. Asian J. 2016, 991–995.

8.    Bin Rao, Huarong Tang, Xiaoming Zeng*, Liu Liu, Mohand Melaimi, Guy Bertrand*, Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong s-Donating and p-Accepting Ligands for Transition Metals, Angew. Chem. Int. Ed. 2015, 54, 14915–14919.

7.    Yu Wei, Bin Rao, Xuefeng Cong, and Xiaoming Zeng*, Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes, J. Am. Chem. Soc. 2015, 137, 9250–9253.

6.    Weixi Zhang, Junyao Xie, Bin Rao, and Meiming Luo*, Iron-Catalyzed N-Arylsulfonamide Formation through Directly Using Nitroarenes as Nitrogen Sources, J. Org. Chem., 2015, 80, 3504–3511.

5.    Bin Rao and Xiaoming Zeng*, Aminocyanation by the Addition of N–CN Bonds to Arynes: Chemoselective Synthesis of 1,2-Bifunctional Aminobenzonitriles, Org. Lett. 2014, 16, 314–317.

4.    Yu Wei, Huarong Tang, Xuefeng Cong, Bin Rao, Chao Wu* and Xiaoming Zeng*,Pd(II)-Catalyzed Intermolecular Arylation of Unactivated C(sp3)–H Bonds with Aryl Bromides Enabled by 8-Aminoquinoline Auxiliary, Org. Lett. 2014, 16, 2248–2251.

3.     Bin Rao, Weixi Zhang, Lan Hu and Meiming Luo*Catalytic desulfitative homocoupling of sodium arylsulfi nates in water using PdCl2 as the recyclable catalyst and O2 as the terminal oxidant, Green Chem. 2012, 14, 3436–3440.

2.    Guangming Nan, Bin RaoMeiming Luo*, Cis-chelated palladium(II) complexes of biphenyl-linked bis(imidazolin-2-ylidene): synthesis and catalytic activity in the Suzuki-Miyaura reaction, ARKIVOC, 2011, ii, 29–40. 1.    

1.   Xiaoqin Zhang, Yuping Qiu, Bin Rao, and Meiming Luo*, Palladium(II)N-Heterocyclic Carbene Metallacrown Ether Complexes: Synthesis, Structure, and Catalytic Activity in the SuzukiMiyaura Reaction, Organometallics 2009, 28, 3093–3099.