论文期刊

论文标题    On-line multi-component alkane mixture quantitative analysis using Fourier transform infrared spectrometer
作者    Xiaojun Tang, Yujun Li, Lingjian Zhu, Anxin Zhao, Junhua Liu
发表/完成日期    2015-07-01
期刊名称    Chemometrics and Intelligent Laboratory Systems
期卷    146
相关文章    On-line Multi-component Alkane Mixture Quantitative Analysis Using Fourier Transform Spectrometer(Final Version).pdf   
论文简介    Fourier transform infrared spectrometer (FTIR) has been widely used to analyze multi-component gas mixture for more than ten years because of its potential benefits. However, it is a challenge to analyze multicomponent alkane mixture on-line with FTIR because their absorption spectra overlap with each other extensively. In this paper, the methods of feature extraction and selection based on Tikhonov regularization (TR), and the modeling methods based on neural network (NN) are discussed in the practical conditions of alkane mixture analysis with FTIR. Then, the proposed methods compared with gas chromatograph (GC), normally regarded as the standardway for quantitative gas analysis, are used for gas well logging to analyze the mixture of methane, ethane, propane, iso-butane and n-butane on-line. By comparing the well logging curves obtained fromFTIRwith the ones fromGC, it is shown that the logging curves analyzed with proposed method are good matches with the ones obtained fromGC,which means that our analysis results are accurate. At the end of this paper, a calibration transfer is used to calibrate additional 18 instrumentswith a fewsets of samples. And thework introduced in this paper demonstrates that FTIR can also be used in analyzing multi-component gas with close molecular structure accurately and the analyzer can be produced in mass.