Blank9

    Yan-Zhen Zheng was born and raised in Guangdong, China. He received his PhD degree in 2007 under Xiao-Ming Chen (Sun Yat-Sen University) for studying low-dimensional magnetic coordination polymers. Yan-Zhen then moved to Europe with the supports of Alexander von Humboldt Fellowship under Annie Powell (Karlsruhe Institute of Technology) and Marie Curie International Incoming Fellowship under Richard Winpenny (The University of Manchester) for advanced molecular magnetism study. During this period he had a short postdoctoral training for spintronics under Paul Kögerler (Forschungszentrum Jülich and RWTH Aachen University). In 2012, he was appointed as a full professor at Xi'an Jiaotong University, where he started his own adventure in molecular magnetism and functional coordination complexes research. In 2014, he was promoted to an associate dean for Frontier Institute of Science and Technology (FIST) and jointly the lab director of molecular spin and electronic structure (MSES). Currently, the research topics in his group mainly focus on the design and synthesis of single-molecule magnets, functional lanthanide clusters, and electrically-conductive coordination compounds.

 

 

 

郑彦臻现为西安交通大学教授,《中国稀土学报》、《中国化学快报》、及Polyoxometalates青年编委,Magnetochemistry编委;2007年博士毕业于中山大学,曾入选德国洪堡学者(2007)、欧盟玛丽居里学者(2009)、国家特聘青年专家(2012)、仲英青年学者(2017)、科技部中青年科技创新领军人才(2018),2021年入选国家重大人才工程(领军人才);其主要研究方向是分子基磁性材料及功能配合物,迄今主持或参与包括国家自然科学基金在内的研究课题共十余项,在JACSAngew ChemNat CommunAdv MaterMatterChem等学术期刊发表论文180余篇。

 

地址陕西省西安市雁翔路99号交大科技园西二楼A202-1,邮编710054

联系方式:zheng.yanzhen@xjtu.edu.cn

课题组网页http://gr.xjtu.edu.cn/web/zheng.yanzhen   

Research ID: http://www.researcherid.com/rid/A-1917-2011  

 

教育背景  

2002-2007

博士,无机化学专业(中山大学)

1998-2002

学士,应用化学专业(中山大学)

           

工作经历    

2011-

前沿科学技术研究院教授(西安交通大学)

20197

2018-

法国波尔多大学及帕斯卡研究中心访问教授

前沿科学技术研究院荣誉副院长(西安交通大学)

2014-2018

前沿科学技术研究院副院长(西安交通大学)

2009-2011

欧盟玛丽居里学者(英国曼彻斯特大学)

2009-2009

博士后研究助理(德国亚琛工业大学)

2007-2009

洪堡学者(德国卡尔斯鲁厄大学)

 

获奖情况    

2019

陕西省高等学校科学技术奖励二等奖

2018

中华医学会一等奖(第六)

2017

亚洲国际学术论坛杰出授课奖

2013

广东省科学技术(自然类)一等奖(第三)

2009

欧盟居里夫人奖学金(Marie Curie Fellowship

2007

德国洪堡奖学金(Humboldt Fellowship

  

研究方向    

 配位化学、金属有机、功能团簇、分子磁体、分子导体、磁电耦合    

 

基金项目    

1.  国家自然科学基金委面上项目,低价态稀土单分子磁体的构筑与性质研究,223751572024-2027

2.  国家自然科学基金委面上项目,含氟稀土团簇的设计合成及其磁、光性质研究,219712032020-2023

3. 金属材料强度国家重点实验室开放课题,20182016,分子基磁性材料的可控合成与理论研究,2018-2020    

4.  国家自然科学基金委面上项目,21773130,赝两配位单分子磁体的磁构关系、可控合成及高性能化研究,2018-2021    

5.  国家自然科学基金委重点国际(地区)合作研究项目,21620102002, 低维磁分子固体的结构设计与功能调控,2017-2021    

 

代表论文(*为通讯作者)    

 

1.Bis-Alkoxide Dysprosium(III) Crown Ether Complexes Exhibit Tunable Air Stability and Record Energy Barrier; Wen-Jie Xu, Qian-Cheng Luo, Zi-Han Li, Yuan-Qi Zhai, and Yan-Zhen Zheng* Adv. Sci. 2024, article accepted. DOI: 10.1002/advs.202308548. (IF=15.1) 

 

2.Gd-based Molecular Coolants: Aggregating for Better Magnetocaloric Effect; Yuan-Qi Zhai, Wei-Peng Chen,* Marco Evangelisti, Zhendong Fu and Yan-Zhen Zheng* Aggregate 2024, article accepted. (IF=18.8)

 

3. Thermally Stable Terbium(II) and Dysprosium(II) Bis-amidinate Complexes; Peng-Bo Jin, Qian-Cheng Luo, Gemma K. Gransbury, Iñigo J. Vitorica-Yrezabal, Tomáš Hajdu, Ilya Strashnov, Eric J. L. McInnes, Richard E. P. Winpenny, Nicholas F. Chilton*, David P. Mills*, and Yan-Zhen Zheng* J. Am. Chem. Soc. 2023, 145, 27993–28009. (IF = 15) Link

 

4.Mitigating Raman relaxation for high-temperature single-molecule magnets; Qian-Cheng Luo and Yan-Zhen Zheng* Trends Chem. 2023, 5, 869-872. (IF=15.7) Link

 

5.Suppression of zero-field quantum tunneling of magnetization by a fluorido bridge for a "very hard" 3d-4f single-molecule magnet; Bo-Kai Ling, Yuan-Qi Zhai, Peng-Bo Jin, Hong-Fan Ding, Xu-Feng Zhang, Yi Lv, Zhendong Fu, Jiewei Deng, Michael Schulze, Wolfgang Wernsdorfer, Yan-Zhen Zheng* Matter2022, 3485-3498. (IF=18.9) LINK

 

6.{ScnGdn} Heterometallic Rings: Tunable Ring Topology for Spin Wave Excitations; Hao-Lan Zhang, Yuan-Qi Zhai, Hiroyuki Nojiri, Christian Schröder, Hung-Kai Hsu, Yi-Tsu Chan, Zhendong Fu, Yan-Zhen Zheng* J. Am. Chem. Soc. 2022, 144, 15193–15202. (IF = 15)  Link 

 

7.Ligand Fluorination to Mitigate the Raman Relaxation of Dy(III) Single-Molecule Magnets: A Combined Terahertz, Far-IR and Vibronic Barrier Model Study; Yan Ma,Yuan-Qi Zhai,Qian-Cheng Luo,You-Song Ding,Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2022, e202206022. (IF = 16.6) LINK

​​​​​​

8.Tetraanionic arachno-Carboranyl Ligand Imparts Strong Axiality to Terbium(III) Single-Molecule Magnets; Peng-Bo Jin, Ke-Xin Yu, Qian-Cheng Luo, Ye-Ye Liu, Yuan-Qi Zhai and Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2022, e202203285. (IF = 16.6)LINK

 

9.Reentrant Spin Glass and Large Coercive Field Observed in a Spin Integer Dimerized Honeycomb Lattice; Yuan‐Qi Zhai,Yi‐Fei Deng ,Zhendong Fu*,Erxi Feng ,Yixi Su ,Takuya Shiga ,Hiroki Oshio and Yan‐Zhen Zheng* Adv. Funct. Mater. 2021, 31, 2004744,   (IF = 19, featured on back cover)  Link

 

10.Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization; Ke-Xin Yu, Jon G.C. Kragskow,You-Song Ding, Yuan-Qi Zhai, Daniel Reta, Nicholas F. Chilton*, Yan-Zhen Zheng* Chem2020, 6, 1777-1793, (IF = 23.5link

 

11.Single-Molecule Toroic Design through Magnetic Exchange Coupling; Hao-Lan Zhang, Yuan-Qi Zhai, Lei Qin, Liviu Ungur, Hiroyuki Nojiri, Yan-Zhen Zheng* Matter2020, 2, 1481-1493, (IF=18.9, featured on coverlink

 

12.The Gigantic {Ni36Gd102} Hexagon: A Sulfate-Templated “Star-of-David” for Photocatalytic CO2 Reduction and Magnetic Cooling; Wei-Peng Chen, Pei-Qin Liao, Peng-Bo Jin, Lei Zhang, Bo-Kai Ling, Shi-Cheng Wang, Yi-Tsu Chan, Xiao-Ming Chen, and Yan-Zhen Zheng* J. Am. Chem. Soc. 2020, 142, 4663–4670 (IF = 15, featured on cover)  link

 

13. Dysprosiacarboranes: A New Type of Organometallic Single‐Molecule Magnet; Peng-Bo Jin, Yuan-Qi Zhai, Ke-Xin Yu, Richard E. P. Winpenny, and Yan-Zhen Zheng* Angew. Chem. Int. Ed. 2020, 59, 9350-9354 (IF = 16.6)  link

 

14. Field- and temperature-dependent quantum tunnelling of the magnetisation in a large barrier single-molecule magnet;  Y. -S. Ding , K.-X. Yu , D.Reta, F.Ortu, R. E.P. Winpenny , Y.-Z. Zheng*, Nicholas F. Chilton*,  Nat. Commun.20189, 3134 (IF = 16.6)   link 

 

15. Quantum Monte Carlo simulations of a giant {Ni21Gd20} cage with a S =91 spin ground  state; W.-P. Chen, J. Singleton, L. Qin, A. Camón, L. Engelhardt,* F. Luis, R. E. P. Winpenny,* and Y.-Z. Zheng*, Nat. Commun.2018,  9, 2107 (IF = 16.6)  link   

 

16. Quantum Monte Carlo Simulations and High-Field Magnetization Studies of Antiferromagnetic Inter-actions in a Giant Hetero-Spin Ring; L. Qin, J. Singleton, W.-P. Chen, H. No-jiri, L. Engelhardt,* R. E. P. Winpenny,* and Y.-Z. Zheng*, Angew. Chem. Int. Ed.201756, 16571-16574. (IF = 16.6) link

 

17. Topological Self-Assembly of Highly-Symmetric Lanthanide Clusters: A Magnetic Study of Exchan-ge-Coupling “Fingerprints” in Giant Gadolinium(III) Cages; L. Qin, G.-J. Zhou, Y.-Z. Yu, H. Nojiri, C. Schröder*, R. E. P. Winpenny* and Y.-Z. Zheng*, J. Am. Chem. Soc.2017139, 16405–16411. (IF = 15)   link

 

18. On Approaching the Limit of Molecular Magnetic AnisotropyA Near-Perfect Pentagonal Bipyram-idal Dysprosium(III) Single-Molecule Magnet; Y.-S. Ding, N. F. Chilton,* R. E. P. Winpenny,* and Y.-Z. Zheng*, Angew. Chem. Int. Ed., 201655, 16071–16074. (IF = 16.6,  ESI hot paper)   link

 

19. A “Molecular Water Pipe”: A Giant Tubular Cluster {Dy72} Exhibits Fast Proton Tra-nsport and Slo-w Magnetic Relaxation; L. Qin, Y.-Z. Yu, P.-Q. Liao, W. Xue, Z. Zheng, X.-M. Chen and Y.-Z. Zheng*, Adv. Mater., 201628, 10772–10779. (IF = 29.4) link

 

20. A Mixed-Ligand Approach for a Gigantic and Hollow Heterometallic Cage {Ni64RE96} for Gas Sep-aration and Magnetic Cooling Applications; W.-P. Chen, P.-Q. Liao, Y. Yu, Z. Zheng, X.-M. Chen and Y.-Z. Zheng*, Angew. Chem. Int. Ed.201655, 9375-9379. (IF = 16.6) link

 

21. Molecule-based magnetic coolers;  Y.-Z. Zheng*, G.-J. Zhou, Z. Zheng, R. E. P. Winpenny, Chem. Soc. Rev., 201443, 1462-1475. (入选ESI高被引, IF = 46.2) link 

 

22. A symbol approach for classification of molecule-based magnetic materials exemplifi-ed by coordi-nation polymers of metal carboxylates;  Y.-Z. Zheng*, Z. Zheng, X.-M. Chen, Coord. Chem. Rev., 2014258-259, 1-15. (入选ESI高被引, IF = 20.6) link

 

23. Co-Ln Mixed-Metal Phosphonate Grids and Cages as Molecular Magnetic Refrigerants; Y.-Z. Zheng, M. Evangelisti, F. Tuna, R. E. P. Winpenny,* J. Am. Chem. Soc.2012134, 1057-1065. (入选ESI高被引, IF = 15)

 

24. Large Magnetocaloric Effect in a Wells-Dawson Type {Ni6Gd6P6} Cage; Y.-Z. Zheng, M. Evangelisti, R. E. P. Winpenny,* Angew. Chem. Int. Ed.201150, 3692-3695. (入选ESI高被引, IF = 16.6)    

 

25. Néel Temperature Enhancement by Increasing the In-plane Magnetic Correlati-on in Layered Inorganic–Organic Hybrid Materials; Y.-Z. Zheng, W. Xue, S.-L. Zheng, M.-L. Tong and X.-M. Chen, Adv. Mater., 2008, 20,1534-1538. (IF = 29.4)

 

26. A “Star” Antiferromagnet: A Polymeric Iron(III) Acetate That Exhibits Both Spin-Frustration and Long-Range Magnetic Ordering; Y.-Z. Zheng, M.-L. Tong, W. Xue, W.-X. Zhang, X.-M. Chen, F. Grandjean, G. J. Long,  Angew. Chem. Int. Ed.2007, 46, 6076-6080. (入选ESI高被引, IF = 16.6)

 

27. Assembling Magnetic Nanowires into Network: A Layered Co(II)-Carboxylate C-oordination Polymer Exhibiting Single-Chain-Magnet Behavior; Y.-Z. Zheng, M.-L. Tong, W.-X. Zhang, X.-M. Chen, Angew. Chem. Int. Ed.2006, 45, 6310-6314. (入选ESI高被引, IF = 16.6)    

  

书籍章节

1.Han Tian, You-Song Ding, and Yan-Zhen Zheng. "Lanthanide Clusters Toward Single-Molecule Magnets." 2016, pp209-314,  LINK

2. You-Song Ding, Richard E. P. Winpenny and Yan-Zhen Zheng. “Comprehensive Coordination Chemistry III——3d- and 4f-Based Single Molecule Magnets”. 2021, pp595-619, LINK

3. Hao-Lan Zhang, Yuan-Qi Zhai, and Yan-Zhen Zheng. "Rationalization of Room-Temperature Single-Molecule Toroics via Exchange Coupling", 2022, pp107-131, LINK

4. 郑彦臻, 童明良. “磁性配位聚合物”, 配位聚合物化学(下册) 卜显和主编, 科学出版社, 2019, pp153-192. ISBN:978-7-03-060762-1. LINK

 

专利公开    

1. 郑彦臻,王艳艳,秦雷, 周国军,一种含稀土氢氧化物的磁制冷材料及制备方法,发明专利,专利号:ZL 2014 1 0817811.0    

2. 郑彦臻,凌博恺,“一种氟桥连稀土分子磁制冷材料及制备方法”,发明专利,专利号:ZL 2019 1 1368861.4

3. 郑彦臻,凌博恺,“一种氟桥连稀土分子簇荧光材料及制备方法”,发明专利,专利号:ZL 2019 1 1370953.6

 

学生培养    

1. 已出站博士后3名:韩甜(现在西安交通大学理学院新讲师)、冷际东(现在广东工业大学副教授)、王艳艳(现在陕西师范大学师资博士后);    

2. 已毕业博士生8名:秦雷(南方科技大学、校长卓越博士后)、胡月桥(宝鸡文理学院、讲师)、丁友松(英国曼彻斯特大学博士后)、陈伟鹏(西安交大专职科研博后)、周国军(陕西师范大学师资博士后、国家博新计划获得者)、邓义飞(南方科技大学)、张涛(西北工业大学)、李木清(南方科技大学);    

3. 已毕业硕士生6名:李腾(英国St Andrew’s University攻读博士学位)、吴涛、葛宁、刘炳成、毕乐雨、翟沅琦。    

 

国际交流    

1. 2019106-11日邀请德国比勒菲尔德应用科学大学的Christian Schröder教授来访,做“Exploring Magnetism at the Nano and Micro Scale with Classical Spin Dynamics Methods”的报告并并给学生讲学。

2. 2019921-25日邀请新加坡国立大学的Liviu Ungur助理教授来访,做“Ab initio description of electronic structure and properties of materials”的报告并并给学生讲学。

3. 20197月,应邀赴法国波尔多大学及帕斯卡研究中心(CRPP)做为期一个月的访问教授。

4. 2019227-36,应邀赴日本东北大学的材料研究所Nojiri教授课题组,开展高频高场电子顺磁共振及低温高场磁化强度的实验研究,并访问了东北大学Yamashita教授课题组。

5. 201842日邀请英国曼彻斯特大学的Nicholas Chilton博士于来访,做题为f-Elements as a Playground for Magnetic Phenomena的学术报告并给学生讲学。    

6. 2018315日,受Osamu Sato教授邀请前往日本九州大学参加2018 IMCE International Symposium“Session for Rising Star in Asia”作邀请报告。    

7. 2017125-11日邀请法国国家科学研究院帕斯卡研究中心研究员Rodolphe Clérac研究员来西安交通大学作讲座报告,并连续三天给学生讲授磁性课程。    

8. 20171122-25日邀请日本东北大学山下正广教授来访并作报告,期间山下教授给同学进行博士预答辩。    

9. 2017116-8日受邀在德国比勒费尔德大学举办的分子磁体会议做题为Barrier Engineering of Dysprosium(III) Single-Ion Magnets with an Equatorially-assisted Pseudo-Two-Coordinate Model学术报告。    

10. 2017521-25日邀请日本东北大学的Hiroyuki Nojiri教授进行访问,期间达成多项合作开展研究的项目。    

11. 2017315-19日受Hiroki Oshio教授邀请前往日本筑波大学做学术报告,并于317日前往在东京领Keio大学举办的97届日本化学年会,领取日本化学会颁与的亚洲国际学术论坛杰出授课奖Distinguish Lectureship Awards in Asian International Symposium)。    

12. 20161017日到1018日,邀请来自德国斯图加特大学的Petr Neugebauer博士来访并作报告,与组内同学交流。    

13. 201644-6日邀请英国曼彻斯特大学的Richard Winpenny教授进行访问,并聘请Winpenny教授为西安交大客座教授。    

14. 2015312-15日邀请日本东北大学的Masahiro Yamashita教授进行访问,聘请山下正广教授为西安交大客座教授。