发布时间：2026-06-30

DOI码：10.1021/jacs.5c03381

论文名称：Chirality-Contiguous Bridged Carboranes: Synergistic Scalable Synthesis and Amplification of Circularly Polarized Luminescence

发表刊物：J. Am. Chem. Soc

关键字：Chirality (physics); Luminescence; Chemistry; Combinatorial chemistry; Enantioselective synthesis; Chromophore; Carborane; Molecule; Stereochemistry

摘要：Icosahedral carboranes are promising structural motifs for optoelectronic functional materials owing to their unique three-dimensional aromatic architectures and distinctive electronic properties. However, their applications remain restricted by the absence of efficient and scalable asymmetric synthesis and limited circularly polarized luminescence (CPL) studies. Herein, we developed a highly stereoselective and straightforward asymmetric synthesis for chiral carborane molecules. This method employs readily available starting materials and enables the precise construction of optically pure ch…

合写作者：He P, Zhang T, Dong Y, Feng C, He T, Li P, Zhang Y, Nie Y, Jiao J

第一作者：Nan L

论文类型：期刊论文

通讯作者：Zhang Y, Nie Y, Jiao J

论文编号：128

ISSN号：0002-7863;1520-5126;1943-2984

是否译文：否

发表时间：2025-06-30

收录刊物：SCI

发布期刊链接：https://doi.org/10.1021/jacs.5c03381