张涛论文在ACS Appl. Mater. Interfaces上发表
- 发布时间：
- 2017-10-31
- 文章标题：
- 张涛论文在ACS Appl. Mater. Interfaces上发表
- 内容：
张涛在ACS Applied Materials & Interfaces上发表题为“A Cobalt(II) Magnetic Metal-Organic Framework with an Effective Kagomé Lattice, Large Surface Area and High SpinCanted Ordering Temperature”的论文。
论文TOC
Abstract: To make a porous material with high magnetic ordering temperature is challenging because the low density of the material is adverse to the dense magnetic moment, a prerequisite to high-performance magnets. Herein, we report a hollow magnetic metal-organic framework (MMOF) [Co3(bpdc)3(tpt)0.66] 1 (H2bpdc = 4,4'-biphenyldicarboxylic acid) with a Langmuir surface area of 1118 m2/g and spincanted long-range magnetic ordering up to 22 K. Such a high performance is owing to the unique antiferromagnetic Kagomé lattice made of ferromagnetic Co3 clusters and conjugated 2,4,6-tri(4-pyridinyl)-1,3,5-triazine (tpt) ligands, which is closely coupled with each other via doubleinterpenetration of the porous networks.
论文链接：link