An experimental study of premixed laminar methane-oxygen-argon flames doped with with hydrogen at low pressure with synchrotron photoionization (PDF)
发布时间：2025-04-30
点击次数：
- 发布时间：
- 2025-04-30
- 论文名称：
- An experimental study of premixed laminar methane-oxygen-argon flames doped with with hydrogen at low pressure with synchrotron photoionization (PDF)
- 发表刊物：
- Chinese Science Bulletin
- 摘要：
- Laminar premixed stoichiometric methane/hydrogen/oxygen/argon flames were investigated with tunable
synchrotron vacuum ultraviolet (VUV) photoionization and molecular-beam sampling mass spectrometry techniques. The methane/hydrogen fuel blends with hydrogen volumetric fraction of 0, 20%,
40%, 60% and 80% were studied. All observed flame species, including stable intermediates and radicals in the flames, were detected by measuring photoionization mass spectra and photoionization efficiency
(PIE) spectra. Mole fraction profiles of major species and intermediates were derived by scanning burner at some selected photon energies near ionization thresholds. The influence of hydrogen addition on mole fraction of major species and intermediates was analyzed. The results show that the
major species mole fraction of CO, CO2 and CH4 decreases with the increase of hydrogen fraction. The mole fraction of intermediates measured in this experiment decreases remarkably with the increase of
hydrogen fraction. This would be due to the increase of H and OH radicals by hydrogen addition and the high diffusivity and activity of H radical promoting the chemical reaction. In addition, the increase of H/C ratio with the increase of hydrogen fraction also leads to the decrease of the mole fraction of carbon-
related intermediates and contributes to the decrease of unburned and incomplete combustion products
- 合写作者：
- Wang JH, Hu EJ, Huang ZH
- 卷号：
- 2008, 53(8):1262-1269
- 页面范围：
- 1262-1269
- 是否译文：
- 否
- 发表时间：
- 2008-04-15